Post-synthesis modification of metal–organic frameworks: synthesis, characteristics, and applications

Abstract

Post-synthesis modification (PSM) is an efficient means to introduce functional chemical groups into metal–organic frameworks (MOFs) by modifying metal clusters or ligands after MOFs have been synthesized.

Structure–property–performance relationship of vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications

“…Unique configurations, adjustable pores, and surface performance of MOFs can be designed by self-assembly and post-synthesis modifications, leading to better performance than conventional materials. 72–74 Accordingly, the successful modulation of different organic and inorganic catalytic elements has been carried out in active MOF-localized sites. 75 However, MOFs can only be functionalized with efficient and localized catalytically active components while controlling the conditions and considering clear-cut assumptions.…”

Sulfonated Azocalix[4]arene-Modified Metal–Organic Framework Nanosheets for Doxorubicin Removal from Serum

“…The SAC4A/CSAC4A loaded adsorbents were synthesized through the post-synthesis modification of MOF nanosheets [43]. In the synthesis of SAC4A-loaded NUS-8 nanosheets (N@SAC4A), as-prepared NUS-8 nanosheets (50 mg) were dispersed in DMF (10 mL) by 30 min of ultrasonication.…”

Copper peroxide nanodot-decorated gold nanostar/silica nanorod Janus nanostructure with NIR-II photothermal and acid-triggered hydroxyl radical generation properties for the effective treatment of wound infections

“…3,4 Recently, nanomaterial-based photothermal therapy (PTT) has attracted enormous interest in antibacterial applications, mainly due to its easy operation, high antibacterial efficiency and slim chance of inducing bacterial resistance. 5,6 The photothermal effect-induced heat elevation can effectively kill bacteria by ways of breaking the bacterial membrane, denaturing the enzyme activity, causing severe oxidative stress, damaging bacterial DNA, etc. 7 Currently, many types of nanomaterial-based photothermal reagents have been developed for photothermal therapy, including organic dye (i.e., indocyanine green, polypyrrole, melanin)-based assemblies, 8 gold (Au) nanostructures, [9][10][11] carbon-based materials, molybdenum-based materials, 12 and two-dimensional materials (graphene, MXenes, black phosphorus nanosheets, etc.).…”