Positron annihilation studies of methylammonium lead bromide perovskite

Abstract

Methylammonium lead halide-based perovskite has shown excellent optoelectronic properties. But their performances and stability are critically affected by the ionic defects present in the crystal lattice. In this article, we have investigated the presence of ionic vacancy mediated defects formation in ball mill ground methylammonium lead bromide (MAPbBr3) which has applications in tandem solar cell, light emitting diodes and laser devices. The evaluation of those point defects with temperature was analysed by employing the positron annihilation spectroscopic (PAS) studies. The phase transition from tetragonal to cubic phases around 260 K was exactly correlated with the temperature-dependent ‘S parameter’ determination from PAS analysis and with dc conductivity measurement. From coincidence Doppler broadening (CDB) spectroscopy significant proportion of defects arising from lead vacancy was observed whose magnitude reduces from the low-temperature tetragonal phase to higher temperature cubic phases.

Reducing hot carrier cooling rate in metal halide perovskites through lead vacancies: time-domain ab initio analysis

“…The presence of Pb V in MAPbI 3 based perovskites has been experimentally identified using positron annihilation lifetime spectroscopy. 36,37 Previous studies have indicated that Pb V can change localization of photoexcited electron and hole states, thereby suppressing radiative and nonradiative electron-hole recombination processes in MHPs. 38,[39][40][41] Understanding the extent to which HC cooling dynamics can be manipulated by Pb V is urgently needed, underscoring the importance of further in-depth theoretical investigations.…”