We first prove the equivalence of two definitions of Riemann−Liouville fractional integral on time scales, then by the concept of fractional derivative of Riemann−Liouville on time scales, we introduce fractional Sobolev spaces, characterize them, define weak fractional derivatives, and show that they coincide with the Riemann−Liouville ones on time scales. Next, we prove equivalence of some norms in the introduced spaces and derive their completeness, reflexivity, separability and some imbeddings. Finally, as an application, by constructing an appropriate variational setting, using the mountain pass theorem and the genus properties, the existence of weak solutions for a class of Kirchhoff-type fractional p-Laplacian systems on time scales with boundary condition is studied, and three results of the existence of weak solutions for this problem is obtained.