For every finite dimensional Lie supergroup (G, g), we define a C * -algebra A := A(G, g), and show that there exists a canonical bijective correspondence between unitary representations of (G, g) and nondegenerate * -representations of A. The proof of existence of such a correspondence relies on a subtle characterization of smoothing operators of unitary representations from [NSZ].For a broad class of Lie supergroups, which includes nilpotent as well as classical simple ones, we prove that the associated C * -algebra is CCR. In particular, we obtain the uniqueness of direct integral decomposition for unitary representations of these Lie supergroups.