Various available codes for NLTE modeling and analysis of hot star spectra are reviewed. Generalizations of standard equations of kinetic equilibrium and their consequences are discussed.
Importance of radiationRadiation is not only an information source about stellar atmospheres, it has also the ability to interact with the matter in the atmosphere and to alter its state.Each photon has a momentum hν/c. Consequently, when it is absorbed, the absorbing ion receives this amount of momentum. If it is scattered, the atom may receive from no momentum (if radiation is scattered in the forward direction) to 2hν/c, if radiation is scattered backwards. This momentum gain is redistributed to other particles by elastic collisions and, as a consequence, acceleration of matter by radiation occurs.The energy of a photon (hν) can also be transferred to matter. In the case of ionization, part of this energy is used to ionize the atom and the rest goes to kinetic energy of electrons, hν → hν ion + 1 2 m e v 2 e . In the case of excitation, all photon energy is used for this process, hν → hν exc . In the case of the free-free absorption the photon energy causes increase of the electron kinetic energy, hν → 1 2 m e ∆ v 2 e . Reverse processes (recombination, deexcitation, and free-free emission) cause release of a photon and lowering the atomic internal or electron kinetic energy (or both). In the above mentioned cases of bound-free and free-free transitions there is an energy exchange with electron kinetic energy. In this case, subsequent elastic collisions reestablish the equilibrium velocity distribution with a slightly different temperature. Consequently, the thermal energy increases or decreases and we talk about radiative