Porous N, P co-doped carbon-coated ultrafine Co2P nanoparticles derived from DNA: An electrocatalyst for highly efficient hydrogen evolution reaction

Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

“…In the first step Au@ZIF-67-3 was calcinated at high temperature under argon atmosphere and at last phosphidation occurred in the presence of NaH 2 PO 2 to obtain Au/CoP@NC-3 (Figure 14d). Li et al [135] fabricated porous N, P-codoped Co 2 P NP from DNA by pyrolysis method, they used DNA as the precursor of N, P-codoped carbon substrate as well as the phosphorous source for Co 2 P NP (Figure 14e). Out of the above-mentioned synthesis methods, a mechanochemical method is the newest for the synthesis of TMP through the shaker mill and planetary mill.…”

“…Li et al. [ 135 ] fabricated porous N, P‐codoped Co 2 P NP from DNA by pyrolysis method, they used DNA as the precursor of N, P‐codoped carbon substrate as well as the phosphorous source for Co 2 P NP (Figure 14e). Out of the above‐mentioned synthesis methods, a mechanochemical method is the newest for the synthesis of TMP through the shaker mill and planetary mill.…”

“…Out of various phases of rhodium phosphides the metal-rich Rh 2 P has been found to be a suitable catalyst for hydroformylation reactions. [135,136] Rupflin et al [273] were the first to utilize the Rh 2 P/SiO 2 for the catalytic hydroformylation of ethylene and propylene to form their corresponding aldehydes. They used phosphoric acid as a phosphorous precursor to synthesize Rh 2 P supported on SiO 2 at high temperature 900 °C.…”

Metal@hollow carbon sphere nanoreactors for sustainable biomass and CO2valorization

“…The N,P co-doped carbon shells could improve the electrical conductivity of electrodes and enhance the electrocatalytic performance towards hydrogen precipitation reactions. 130 Li et al 131 proposed N and S double-doped hollow carbon materials (SZ-HCN) as catalysts for the electrochemical reduction of CO 2 . The SZ-HCN showed outstanding catalytic properties for the reduction of CO 2 to CO at 0.6 V, with a high CO faradaic efficiency (∼93%) and significant electrocatalytic durability.…”

Anodic Etching of Amorphous Ni81P19 Alloy in Hot Concentrated Chloride Solution for Enhanced Hydrogen Evolution in Alkaline Water Electrolysis

“…Additionally, their structure is modulated for obtaining highly porous materials with nanoparticles. [42][43][44] The high activity of such materials was attributed to the high surface area, good electric conductivity, a large number of active sites, and strong interfacial interactions between phosphide particles. [41] Good electroactivity for water splitting is also exhibited by amorphous alloys.…”