Porous Colloidal Nanoparticles as Injectable Multimodal Contrast Agents for Enhanced Geophysical Sensing

Abstract

Injecting fluids into underground geologic structures is crucial for the development of long-term strategies for managing captured carbon and facilitating sustainable energy extraction operations. We have previously reported that the injection of metal–organic frameworks (MOFs) into the subsurface can enhance seismic monitoring tools to track fluids and map complex structures, reduce risk, and verify containment in carbon storage reservoirs because of their absorption capacity of low-frequency seismic waves. Here, we demonstrate that water-based Cr/Zn/Zr MOF colloidal suspensions (nanofluids) are multimodal geophysical contrast agents that enhance near-wellbore logging tools. Based on experimental fluid-only measurements, MIL-101­(Cr), ZIF-8, and UiO-66 nanofluids have distinct complex conductivity and/or low-field nuclear magnetic resonance (NMR) signatures that are relevant to field-deployed technologies, implying the potential to enhance near-wellbore monitoring of CO2 injection and associated processes with downhole logging tools. Small- and wide-angle X-ray scattering characterization of ∼0.5 wt % MIL-101­(Cr) suspensions confirmed phase stability and provided insight into the fractal nature of colloidal nanoparticles. Finally, low-field (2 MHz) NMR measurements of MIL-101­(Cr) nanofluid injection into a prototypical Berea sandstone demonstrate how paramagnetic high-surface area MOFs may dominate the relaxation times of hydrogen-bearing fluids in porous geologic matrices, enhancing the mapping of near-surface and near-wellbore transport pathways and advancing sustainable subsurface energy technologies.

Review of foundational concepts and emerging directions in metamaterial research: design, phenomena, and applications

“…210 Injectable MOF suspensions have been shown to alter the distinct elastic and anelastic properties of rocks, resulting in decreased seismic wave velocities and amplitudes. 65,211 The ability to disperse the contrast agent nanoparticles 212,213 throughout a fluid-rock system allows for the possibility of imposing a 2D or 3D km-scale subsurface meta-structure (Fig. 3C).…”