“…Metal oxide semiconductor gas-sensing materials such as Fe 2 O 3 , SnO 2 , In 2 O 3 , and TiO 2 are widely used in actual equipment. − As one of the most promising metal oxide semiconductor materials, TiO 2 was studied as a sensing material for various gases including H 2 S, CO, H 2 , alcohols, SO 2 , NO, and O 2 . , Several methods were developed to further improve the gas sensitivity of TiO 2 ; acquiring a large specific surface area could increase the contact surface of gas molecules and significantly reduce response time accordingly. − Monolithic porous materials with ultralow densities attract high interests because of their promising prospects as adsorption materials. − Compared to common 2D materials, the unique structure of the TiSiO 4 aerogel generally presents higher specific area, higher porosity, and lower density, which will increase the contact area of gases and lead to shorter response time. , Recently, a three-dimensional TiSiO 4 monolayer membrane was proposed and showed excellent sensing performance toward H 2 S gas; however, the sensing mechanism between H 2 S and the TiSiO 4 membrane at nanoscale is still not clear, which is crucial for designing and developing novel TiSiO 4 gas sensors.…”