2021
DOI: 10.1002/aenm.202100154
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Porosity Engineering of MOF‐Based Materials for Electrochemical Energy Storage

Abstract: energy storage (EES)-primarily supercapacitors and metal-ion batteries (MIBs, e.g., lithium-ion batteries (LIBs), sodiumion batteries (SIBs), and potassium-ion batteries (PIBs)).Both supercapacitors and batteries typically consist of current collectors, electrodes, electrolyte, and a separator. By applying a suitable potential between current collectors, the charge/discharge process takes place mediated by the electrode materials, and the electrolyte ions (i.e., the charge carriers) are accordingly driven to t… Show more

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Cited by 92 publications
(59 citation statements)
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References 280 publications
(619 reference statements)
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“…The pore size of the Ni-BPDC-MOF exhibits a bimodal distribution with a diameter of 1-40 nm, while the calculated average value is calculated as 29.2 nm. The average pore size seems to be higher than that of some common MOFs, which is proved by other BPDC-based MOFs with similar structures [20,32]. The relatively larger surface area and pore size may be due to the micropores produced by the long organic linker BPDC and the mesopores caused by the stacked nanoplates.…”
Section: Resultsmentioning
confidence: 79%
“…The pore size of the Ni-BPDC-MOF exhibits a bimodal distribution with a diameter of 1-40 nm, while the calculated average value is calculated as 29.2 nm. The average pore size seems to be higher than that of some common MOFs, which is proved by other BPDC-based MOFs with similar structures [20,32]. The relatively larger surface area and pore size may be due to the micropores produced by the long organic linker BPDC and the mesopores caused by the stacked nanoplates.…”
Section: Resultsmentioning
confidence: 79%
“…Micro-and mesoporous materials, which have a high specific surface area, large pore volume, uniform morphology and abundant framework components, have been widely used in catalytic, 1 adsorption-separation, 2,3 energy storage, 4 optics 5 and electrical 6 fields. Particularly, metal-organic frameworks (porous coordination polymers, MOFs) obtained by selfassembly of metal clusters and organic ligands have attracted much attention.…”
Section: Introductionmentioning
confidence: 99%
“…Metal organic frameworks (MOFs) are ordered crystal structures formed with metal ions and organic ligands, which are widely employed to prepare porous carbon materials and TMS/heteroatom-doped carbon hybrids. [4,9,23] Among various MOFs, zeolitic imidazolate frameworks (ZIFs) can be easily transformed into homogeneous TMS nanoparticles with N-doped carbon frameworks after calcination under inert atmosphere. Via the ZIF-8 (Zn-ZIF) introduction, Li et al [8] successfully prepared coaxial WS 2-x /ZnS/NC nanofibers with rich sulfur vacancies.…”
Section: Introductionmentioning
confidence: 99%
“…[ 1–3 ] However, due to the uneven global distribution and limited reserves of the Li element, sodium ion batteries (SIBs) with similar working principles to LIBs, easy availability and abundant reserves of the Na element have attracted more attention. [ 4,5 ] The standard electrochemical potential of Na + /Na (−2.71 V vs SHE) is higher than that of Li + /Li (−3.04 V vs SHE). The larger ion radius of Na + (1.02 Å) compared with Li + (0.76 Å) means the slow kinetics and lower energy density for SIBs.…”
Section: Introductionmentioning
confidence: 99%