Collisional excitation of He atoms by 65 and 80 MeV 40 Ar q+ ions (q = 6, 13, 14) was investigated by measuring the intensities I λ (F z ) of He I spectral lines at 401 nm and 447 nm as functions of an electric field −30 < F z < +30 kV cm −1 applied parallel and antiparallel to the ion beam. Well resolved signals of singlet-triplet anticrossings 1snl 1 × 3 with n = 4 and 5 were measured for both field directions in addition to smooth intensity variations of the 1snl 1 −1s2p 1 P lines with n = 7 and 5. The asymmetric signal structure indicates a highly coherent excitation of states with different angular momenta. For comparison, some supplementary measurements of I 447 for proton impact are also reported. The results are discussed within the framework of saddle dynamics and the Paul-trap model. They confirm the Janev-Presnyakov scaling law valid for electric dipole Coulomb excitation, according to which the excitation process is essentially determined by the scaled energies E 0 = E ion /(A • q) of the projectile.