The heat transfer coefficient (HTC, h) and critical heat flux (CHF, q″ CHF ) are two major parameters that quantify boiling performance. The HTC describes the efficiency of boiling heat transfer, defined as the ratio of heat flux (q″) to the wall superheat (ΔT w ), that is, h = q″/ΔT w . Here ΔT w is the temperature difference between the boiling surface and the saturated liquid. In the nucleate boiling regime, the heat flux increases with the wall superheat. However, when the heat flux is sufficiently high, excessive vapor bubbles nucleated on the boiling surface prevent the liquid from rewetting the surface and, in turn, form an insulating vapor film over the surface. This vapor film becomes a thermal barrier that leads to a drastic increase in wall superheat and burnout of a boiling system. This transition from nucleate boiling to film boiling is known as the boiling crisis, where the maximum heat flux is CHF. Enhancing CHF, therefore, can either enable larger safety margins or extend the operational heat flux range for boiling systems. [5] Recent efforts to enhance boiling heat transfer have focused on engineering the working fluid or surface properties. [6] In particular, engineering surface structures have received greater attention owing to the constraints on chemical compatibility or operational conditions which can limit the choice of the working fluid. Representative examples of surface structures that effectively enhance CHF are known to be hemi-wicking surfaces such as micropillars and nanowires. [7] These structures enhance CHF by harnessing thin-film evaporation around pillars and capillary-fed wicking through the structures. [8] Surfaces with microcavities, on the other hand, have shown improved HTC by trapping vapor embryos that promote nucleation. [9] Recently, a combination of microtube and micropillar structures referred to as tube-clusters in pillars (TIP), has shown the ability to tune the HTC and CHF by controlling bubble coalescence while maintaining capillary wicking. [10] Despite the controllability, achieving extreme enhancement of HTC and CHF simultaneously remains challenging due to the intrinsic tradeoff between HTC and CHF associated with nucleation-site density. For example, high nucleation-site density may increase HTC but decrease CHF because extensive bubble coalescence hinders the capillary wicking performance, while the reduced number of nucleation sites will limit the HTC enhancement.Boiling is an effective energy-transfer process with substantial utility in energy applications. Boiling performance is described mainly by the heat-transfer coefficient (HTC) and critical heat flux (CHF). Recent efforts for the simultaneous enhancement of HTC and CHF have been limited by an intrinsic trade-off between them-HTC enhancement requires high nucleation-site density, which can increase bubble coalescence resulting in limited CHF enhancement. In this work, this trade-off is overcome by designing three-tier hierarchical structures. The bubble coalescence is minimized to enhance the ...