2009
DOI: 10.1016/j.jcis.2009.06.020
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Polyvinyl alcohol as the barrier layer in thin film composite nanofiltration membranes: Preparation, characterization, and performance evaluation

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Cited by 101 publications
(59 citation statements)
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“…The TFN membranes show characteristic peaks of PVA appearing at 2940 cm À1 , 2910 cm À1 , 1430 cm À1 , and 1095 cm À1 , which corresponds to CH 2 asymmetric stretching, CH 2 symmetric stretching, CH 2 in-plane scissoring, and CAO stretching vibrations, respectively [18]. The distinct broad band at 3000-3600 cm À1 is due to the stretching vibration of OH groups in the PVA polymer chain and from pendent aldehyde groups from incomplete cross-linking reactions [13,14]. This band intensified as the concentration of aluminosilicate single-walled nanotubes in the PVA matrix increased due to the OH stretching of the hydroxyl groups present in the imogolite [18].…”
Section: Aluminosilicate Single-walled Nanotube Characterizationmentioning
confidence: 99%
See 1 more Smart Citation
“…The TFN membranes show characteristic peaks of PVA appearing at 2940 cm À1 , 2910 cm À1 , 1430 cm À1 , and 1095 cm À1 , which corresponds to CH 2 asymmetric stretching, CH 2 symmetric stretching, CH 2 in-plane scissoring, and CAO stretching vibrations, respectively [18]. The distinct broad band at 3000-3600 cm À1 is due to the stretching vibration of OH groups in the PVA polymer chain and from pendent aldehyde groups from incomplete cross-linking reactions [13,14]. This band intensified as the concentration of aluminosilicate single-walled nanotubes in the PVA matrix increased due to the OH stretching of the hydroxyl groups present in the imogolite [18].…”
Section: Aluminosilicate Single-walled Nanotube Characterizationmentioning
confidence: 99%
“…PVA, cast to a UF support membrane, serves as a selective layer for rejection of divalent ions with notable resistance to fouling [9]. Several studies about the use of PVA membranes for reverse osmosis [10][11][12] and nanofiltration [13][14][15] have been carried out. Most of these membranes focus on enhancing the permeate flux while maintaining high selectivity by improving surface cross-linking and dip-coating methods.…”
Section: Introductionmentioning
confidence: 99%
“…An important application for this kind of membranes involves nanofiltration for water purification. Furthermore, salt rejection might be encouraged in our composition by the presence of PVA [59]. It can be then concluded that other salt compositions should be investigated to minimize salt rejection and allow the correct measurement of IEC on this type of membranes.…”
Section: Water Uptake Swelling Degree and Ion-exchange Capacitymentioning
confidence: 99%
“…This is a direct effect of polymer chains crosslinking of PVA with DGEBA. Characteristically, crosslinking of polymer chains generates tighter and denser structures as those polymer chains would interweave and form larger networks [25]. Those more complex structures will impede the free passage of salt molecules across the membrane.…”
Section: 7mentioning
confidence: 99%