PolyTEMPO electrocatalyst for organic electrosynthesis of benzonitrile from benzyl alcohol

Tran, Luyen Thi; Schille, Benjamin; Francke, Robert

doi:10.51316/jca.2021.015

Vietnam j. catal. adsorp.

2021

DOI: 10.51316/jca.2021.015

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PolyTEMPO electrocatalyst for organic electrosynthesis of benzonitrile from benzyl alcohol

Luyen Thi Tran¹,

Benjamin Schille²,

Robert Francke³

Abstract: Requirements for using Poly (2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PolyTEMPO) as an electrocatalyst for the organic electrosynthesis of benzonitrile from benzyl alcohol were investigated. The research results indicated that PolyTEMPO expressed catalytic activity in the electrosynthesis of benzonitrile from benzyl alcohol in the presence of ammonium acetate. The electrosynthesis yield of benzonitrile from benzyl alcohol with PolyTEMPO catalyst reached the maximum value at 35 °C after 18 hours.

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2024

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State-of-the-Art Advancements in Synthesis of Nitriles from Primary Alcohols

Wu,

Zhang,

Pang

et al. 2024

ACS Catal.

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Nitriles are a versatile family of nitrogen-containing organic compounds widely used in the fields of analytical, synthetic, medicinal, and polymer chemistry. Among the numerous synthetic routes, the conversion of primary alcohols into nitriles is particularly noteworthy due to its benefits of a good atom economy, a diversified substrate scope, concise reaction pathways, and satisfactory catalytic efficiency. Herein, the research progress in the methodologies for converting primary alcohols into nitriles is summarized, including conventional thermal homogeneous catalysis and heterogeneous (ammonoxidation and dehydroamination) catalysis as well as emerging photocatalysis and electrocatalysis. The catalyst systems, reaction mechanisms, substrate compatibility, and current limitations of the different routes are highlighted. Finally, future perspectives of nitrile production on a largescale are proposed from the viewpoints of route characteristics, technological maturity, and fundamental research directions.

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State-of-the-Art Advancements in Synthesis of Nitriles from Primary Alcohols

Wu,

Zhang,

Pang

et al. 2024

ACS Catal.

View full text Add to dashboard Cite

show abstract

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PolyTEMPO electrocatalyst for organic electrosynthesis of benzonitrile from benzyl alcohol

Cited by 1 publication

References 5 publications

State-of-the-Art Advancements in Synthesis of Nitriles from Primary Alcohols

State-of-the-Art Advancements in Synthesis of Nitriles from Primary Alcohols

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