1997
DOI: 10.1021/ma961639j
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Polyphosphazene Block Copolymers via the Controlled Cationic, Ambient Temperature Polymerization of Phosphoranimines

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Cited by 123 publications
(116 citation statements)
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“…4. Synthesis of poly(dichlorophosphazene) from linear chlorophosphazene monomers, followed by chlorine replacement at the macromolecular level [28][29][30][31][32][33][34][35][36]. 5.…”
Section: Basic Polymer Synthesis Processesmentioning
confidence: 99%
“…4. Synthesis of poly(dichlorophosphazene) from linear chlorophosphazene monomers, followed by chlorine replacement at the macromolecular level [28][29][30][31][32][33][34][35][36]. 5.…”
Section: Basic Polymer Synthesis Processesmentioning
confidence: 99%
“…was reported 241 by combining the living anionic ROP route to PFS with the living cationic polymerisation of phosphoranimines [242][243][244] (see Scheme 16). This was achieved by capping living PFDMS anions with an excess of chlorodiphenylphosphine to give PFS-PPh2 after purification.…”
Section: The Formation Of the Organometallic-inorganic Bcp Pfdms-b-pmentioning
confidence: 99%
“…By this method, polyphosphazene block co-polymers are synthesized conveniently and polyphosphazenes are produced with wide range of different macromolecule block structures; for example, polyphosphazene-block-polyphosphazene copolymers [5], poly(ethylene oxide)-block-polyphosphazene co-polymers [36,37] and polystyrene-block polymer phosphazene co-polymers [38,39]. These polymers are utilized for biomedical applications.…”
Section: Cationic/anionic Condensation Polymerizationmentioning
confidence: 99%