Polyoxometalate catalysts in solar fuels

Hill, Craig L.; Song, Jié; Liu, Meilin; Sullivan, Kevin P.; Yin, Qiuxiang; Lauinger, Sarah M.; Snider, Victoria G; Geletii, Yurii V.; Lian, Tianquan; Musaev, Djamaladdin G.

doi:10.1021/scimeetings.0c06106

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Lead-free Halides As Sensitive Scintillators1

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2021

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“…[174] Figure 6a illustrates the crystalline structure of Rb2CuBr3, in which a Cu atom is surrounded by four Br atoms, constituting a distorted tetrahedron [CuBr4] 3-. Similar to previous low-dimensional metal halide perovskite-like materials with STEs, [175][176] a large Stokes shift is presented in Figure 6b. The negligible photoluminescence and photoluminescence excitation (PLE) overlapping indicates a weak self-absorption effect, which is a priorcondition for achieving high LY.…”

Section: Lead-free Halides As Sensitive Scintillatorssupporting

confidence: 86%