Polyoxometalate-based Cu/Zn-MOFs with diverse stereo dimensions as anode materials in lithium ion batteries

Wang, Zikai; Bi, Rong; Liu, Jiadi; Wang, Kuaibing; Mao, Feifei; Wu, Hua; Bu, Yuanqing; Song, Ninghui

doi:10.1016/j.cej.2020.127117

Cited by 32 publications

(22 citation statements)

References 58 publications

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Section: Mofs As Anode Materials For Libsmentioning

confidence: 99%

“…Four recent polyoxometalate‐based MOFs (namely, NAU3/4/5/6 with different morphologies) have been proposed for the anode material of LIBs 44 . All four NAUs (NAU3 through 6) were shown to have some improvement in their electrochemical performance to retain stable reversible capacities of 575.8, 435.5, 314.8, and 362 mAhg −1 respectively 44 . NAU3 retained high reversible capacity than other three because the electrochemical performances depend on the combined effects of various factors (eg, coordinated metals centres [Cu + and Zn 2+ ], redox activity of the cluster anions, and azacycle coordination ability with Li + ).…”

Section: Mofs As Anode Materials For Libsmentioning

confidence: 99%

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Metal‐ organic frameworks and their derivatives as anode material in lithium‐ion batteries: Recent advances towards novel configurations

Kaur

Chhabra

Chaudhary

et al. 2022

Intl J of Energy Research

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Summary Lithium‐ion batteries (LIBs) have drawn extensive research interests due to their noticeably enhanced gravimetric energy density relative to other chemical batteries. The potential utility of metal‐organic frameworks (MOFs) and their derivatives has recently been recognized as highly effective anode components for LIBs because they can be tuned to select specific metal sites and/or to adjust pore sizes. In this work, their electrochemical performance as anodic materials is carefully evaluated with respect to lithium‐ions storage capacity, energy/power, stability, and flexibility. Furthermore, through the coordination of the organic linker and metal center, MOFs can benefit from enhanced catalytic activities in the design of advanced LIBs. For future research for next‐generation LIBs, scientific focus should be placed on the development of diverse features of MOF‐based composites such as core‐shell MOFs, mono/bi‐metal doped MOFs, dual organic linker‐based MOFs, MOFs@MOFs core shell structure, and dual organic ligands‐based MOF. As such, MOF‐based LIB electrode materials are expected to expand their utility with the improvement in topology and functionality in association with the dimensionality, pore size, and surface area.

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Section: Mofs As Anode Materials For Libsmentioning

confidence: 99%

Section: Mofs As Anode Materials For Libsmentioning

confidence: 99%

Metal‐ organic frameworks and their derivatives as anode material in lithium‐ion batteries: Recent advances towards novel configurations

Kaur

Chhabra

Chaudhary

et al. 2022

Intl J of Energy Research

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show abstract

“…This structure allows improving the electrical conductivity and acts as a buffer medium to alleviate the volume change [128]. Furthermore, it allows the development of new polyoxometalate-based metal-organic frameworks (POMOFs) of NAU3-6 with various architectural features [129].…”

Section: Conversion-type Transition-metals and Their Composites-based Anode Active Materialsmentioning

confidence: 99%

Recent Advances on Materials for Lithium-Ion Batteries

et al. 2021

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Environmental issues related to energy consumption are mainly associated with the strong dependence on fossil fuels. To solve these issues, renewable energy sources systems have been developed as well as advanced energy storage systems. Batteries are the main storage system related to mobility, and they are applied in devices such as laptops, cell phones, and electric vehicles. Lithium-ion batteries (LIBs) are the most used battery system based on their high specific capacity, long cycle life, and no memory effects. This rapidly evolving field urges for a systematic comparative compilation of the most recent developments on battery technology in order to keep up with the growing number of materials, strategies, and battery performance data, allowing the design of future developments in the field. Thus, this review focuses on the different materials recently developed for the different battery components—anode, cathode, and separator/electrolyte—in order to further improve LIB systems. Moreover, solid polymer electrolytes (SPE) for LIBs are also highlighted. Together with the study of new advanced materials, materials modification by doping or synthesis, the combination of different materials, fillers addition, size manipulation, or the use of high ionic conductor materials are also presented as effective methods to enhance the electrochemical properties of LIBs. Finally, it is also shown that the development of advanced materials is not only focused on improving efficiency but also on the application of more environmentally friendly materials.

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“…Polyoxometalates (POMs), one kind of nanoscale metal oxygen clusters, [15][16][17] have been considered to be promising candidates as electrode materials for LIBs, due to the multielectron redox properties, high theoretical capacities, and electron storage abilities. [18][19][20][21] In 2011, classical Keggin-type [PMo 12 O 40 ] 3À as the cathode material was studied for the first time, [8] then [PMo 12 O 40 ] 3À was found to undergo a reversible 24 electrons redox during the charging/discharging. [23,24] How to design and construct a perfect composite with the advantages of POMs, CoS 2 /MoS 2 , and highly conductive substrates?…”

Section: Introductionmentioning

confidence: 99%

Nanohybridization of CoS₂/MoS₂ Heterostructure with Polyoxometalate on Functionalized Reduced Graphene Oxide for High‐Performance LIBs

Wang

et al. 2022

Chemistry A European J

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To address the poor cycling stability and low rate capability of MoS 2 as electrode materials for lithium-ion batteries (LIBs), herein, the CoS 2 /MoS 2 /PDDA-rGO/PMo 12 nanocomposites are constructed via a simple hydrothermal process, combining the advantages of all three, namely, CoS 2 / MoS 2 heterojunction and polyoxometalates (POMs) provide abundant catalytically active sites and increase the multielectron transfer ability, and the positively charged poly(diallyldimethylammonium chloride) modified reduced graphene oxide (PDDA-rGO) improve electronic conductivity and effectively prevent the aggregation of MoS 2 , meanwhile stabilize the negatively charged [PMo 12 O 40 ] 3À . After the electrochemical testing, the resulting CoS 2 /MoS 2 /PDDA-rGO/ PMo 12 nanocomposite achieved 1055 mA h g À 1 initial specific capacities and stabilized at 740 mA h g À 1 after 150 cycles at 100 mA g À 1 current density. And the specific capacities of MoS 2 , MoS 2 /PDDA-rGO, CoS 2 /MoS 2 , and CoS 2 /MoS 2 /PDDA-rGO were 201, 421, 518, and 589 at 100 mA g À 1 after 150 cycles, respectively. The fact of the greatly improving capacity of MoS 2 -based nanocomposites suggests its potential for high performance electrode materials of LIBs. Moreover, the lithium storage mechanism of CoS 2 /MoS 2 /PDDA-rGO/PMo 12 has been discussed on the basis of cyclic voltammetry with different scan rates.

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Polyoxometalate-based Cu/Zn-MOFs with diverse stereo dimensions as anode materials in lithium ion batteries

Cited by 32 publications

References 58 publications

Metal‐ organic frameworks and their derivatives as anode material in lithium‐ion batteries: Recent advances towards novel configurations

Metal‐ organic frameworks and their derivatives as anode material in lithium‐ion batteries: Recent advances towards novel configurations

Recent Advances on Materials for Lithium-Ion Batteries

Nanohybridization of CoS₂/MoS₂ Heterostructure with Polyoxometalate on Functionalized Reduced Graphene Oxide for High‐Performance LIBs

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Polyoxometalate-based Cu/Zn-MOFs with diverse stereo dimensions as anode materials in lithium ion batteries

Cited by 32 publications

References 58 publications

Metal‐ organic frameworks and their derivatives as anode material in lithium‐ion batteries: Recent advances towards novel configurations

Metal‐ organic frameworks and their derivatives as anode material in lithium‐ion batteries: Recent advances towards novel configurations

Recent Advances on Materials for Lithium-Ion Batteries

Nanohybridization of CoS2/MoS2 Heterostructure with Polyoxometalate on Functionalized Reduced Graphene Oxide for High‐Performance LIBs

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Nanohybridization of CoS₂/MoS₂ Heterostructure with Polyoxometalate on Functionalized Reduced Graphene Oxide for High‐Performance LIBs