2007
DOI: 10.1088/0957-4484/18/22/225601
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Polyol-mediated thermolysis process for the synthesis of MgO nanoparticles and nanowires

Abstract: The main aim of this work is to prepare MgO nanoparticles and nanowires by a novel polyol-mediated thermolysis (PMT) process. The influence of different mole concentration of magnesium acetate, polyvinyl pyrrolidone (PVP; capping agent) and ethylene glycol (EG; solvent as well as reducing agent) on the formation of nanoparticles and nanowires and the effect of calcination on the crystalline size of the samples were also examined. The resultant oxide structure, thermal behaviour, size and shape have been studie… Show more

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Cited by 54 publications
(29 citation statements)
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References 34 publications
(33 reference statements)
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“…Many factors such as temperature, time, pH, catalytic agent for gel formation, and the environmental conditions can significantly affect the characteristics of the nanoparticles (Klabunde et al, 1996;Bokhimi et al, 1995). The advantages of the sol-gel method are simplicity, cost effectiveness, high yield of nanoparticles, and low reaction temperature (Jiu et al, 2003;Bokhimi et al, 1999;Subramania et al, 2007). Stengl et al (2004) described the preparation of magnesium hydroxide aerogels on the basis of the hydrolysis and condensation reactions of the alkoxide.…”
Section: Sol-gel Methodsmentioning
confidence: 99%
“…Many factors such as temperature, time, pH, catalytic agent for gel formation, and the environmental conditions can significantly affect the characteristics of the nanoparticles (Klabunde et al, 1996;Bokhimi et al, 1995). The advantages of the sol-gel method are simplicity, cost effectiveness, high yield of nanoparticles, and low reaction temperature (Jiu et al, 2003;Bokhimi et al, 1999;Subramania et al, 2007). Stengl et al (2004) described the preparation of magnesium hydroxide aerogels on the basis of the hydrolysis and condensation reactions of the alkoxide.…”
Section: Sol-gel Methodsmentioning
confidence: 99%
“…[37] Magnesium acetate tetrahydrate (0.05 mol) and PVP (0.3 mmol) as capping agent were dissolved in EG in a round-bottom flask. The solution was refluxed at 473 K, with constant stirring, for 2 h to obtain a white flocculate.…”
Section: Methodsmentioning
confidence: 99%
“…However, the useful properties of MgO are further enhanced when used as nano-size powder with novel nano structures. Many different synthetic routes provide nanoscale MgO including sol-gel [8], hydrothermal/solvothermal [9,10], laser vaporization [11], chemical gas phase deposition [12], aqueous wet chemical method [13], surfactant methods [14], polyol-mediated thermolysis process [15]. In the above mentioned methods, limitations such as requirement of sophisticated equipments, many processing steps, more time, template, surfactant, and energy dissipation in the preparation of MgO nanostructures were observed.…”
Section: Introductionmentioning
confidence: 99%