Polynuclear trivalent metal complexes with phosphonic acids

Rao, B. Venkateswara; Palta, Neelam; Puri, D. M.; Sharma, Neha

doi:10.1007/bf01025674

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Molecular Catalysts1

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2020

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“…4a, confirming the conclusions reached by NMR investigation. To the best of our knowledge, this is the first dinuclear EDTMP complex thoroughly characterized by NMR and single crystal X-ray diffraction; rare examples of analogous compounds were reported for some first row transition metals like Fe, Ni and Cu several decades ago [92][93][94]. Ir-H4-EDTMP exhibits a highly symmetric structure with an inversion point lying in the middle of the ethylene bridge (Fig.…”

Section: Molecular Catalystsmentioning

confidence: 99%

Molecular and heterogenized dinuclear Ir-Cp* water oxidation catalysts bearing EDTA or EDTMP as bridging and anchoring ligands

et al. 2020

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The development of efficient water oxidation catalysts (WOCs) is of key importance in order to drive sustainable reductive processes aimed at producing renewable fuels. Herein, two novel dinuclear complexes, [(Cp*Ir)2(μκ 3 -O,N,O-H4-EDTMP)] (Ir-H4-EDTMP, H4-EDTMP 4− = ethylenediamine tetra(methylene phosphonate)) and [(Cp*Ir)2(μ-κ 3 -O,N,O-EDTA)] (Ir-EDTA, EDTA 4− = ethylenediaminetetraacetate), were synthesized and completely characterized in solution, by multinuclear and multidimensional NMR

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Section: Molecular Catalystsmentioning

confidence: 99%