1992
DOI: 10.1016/s0020-1693(00)83797-4
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Polynuclear transition metal complexes. The reactivity of the new potentially binucleating ligand 2, 6-diacetylpyridine-bis(1′-phthalazinylhydrazone) towards NiII, CuII and ZnII salts, and crystal and molecular structure of {bis[2,6-diacetylpyridine-bis(1′-phthalazinylhydrazonato)nickel(II)]} dimethylformamide and water solvate

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Cited by 55 publications
(24 citation statements)
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“…This does not occur in complex 5, leading to a less symmetrical compound. However all the bond distances and angles are comparable between the complexes and are in the range of those expected for Ni complexes with hydrazone ligands [16,21,23].…”
Section: Crystal Structure Of [Ni 2 (H 2 Daps) 2 (Ch 3 Oh) 2 ]´3 Ch 3supporting
confidence: 58%
“…This does not occur in complex 5, leading to a less symmetrical compound. However all the bond distances and angles are comparable between the complexes and are in the range of those expected for Ni complexes with hydrazone ligands [16,21,23].…”
Section: Crystal Structure Of [Ni 2 (H 2 Daps) 2 (Ch 3 Oh) 2 ]´3 Ch 3supporting
confidence: 58%
“…To verify this, the aforementioned electrochemical reaction was performed in the presence of other electrolytes, such as NH 4 PF 6 , N(CH 3 ) 4 Br, or N(CH 2 CH 2 CH 2 CH 3 ) 4 Br. In the case of NH 4 PF 6 , the reaction yielded 1, as one would expect in view of the poor nucleophilicity of PF 6 Ϫ . The use of the bromide electrolytes led to transparent yellow acetonitrile solutions, rather than to the insoluble complex 1.…”
Section: Resultsmentioning
confidence: 71%
“…A survey of literature reveals that although work on metal complexes of monohydrazide-based ligands and their Schiff bases has been carried out in some detail [18][19][20][21], those on metal complexes of dihydrazones are quite meager [16,17,[22][23][24][25][26][27]. It further reveals that work on heterobimetallic complexes of dihydrazones is virtually absent [26,27].…”
Section: Introductionmentioning
confidence: 99%