Polymorphism in A<sub>3</sub>MF<sub>6</sub> (A = Rb, Cs; M = Al, Ga) grown using mixed halide fluxes

Morrison, Gregory; Masachchi, Lakshani W.; Tisdale, Hunter B.; Chang, Tieyan; Jones, Virginia G.; Zamorano, K. Pilar; Breton, Logan S.; Smith, Mark D.; Chen, Yu-Sheng; zur Loye, Hans-Conrad

doi:10.1039/d3dt00352c

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2024

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Fluorides: Inorganic Solid‐State and Structural Chemistry

Kraus

2024

Encyclopedia of Inorganic and Bioinorganic Chemistry

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After an introduction of what is special in solid‐state fluorine chemistry, different synthetic methods relevant to the field are discussed. These span the whole range from classical solid‐state syntheses, over synthesis in solution to gas‐phase synthesis including modern tools like photochemistry. The following structural chemistry section explains the crystal structures and their structural relationships among selected binary, ternary, and quaternary fluorides. A discussion on the physical properties of fluorides such as magnetism, electrical conductivity, ionic conductivity, fluoride ion batteries, and phosphors for light‐emitting diodes (LEDs) follows. We close with a chapter called “Beyond the Standard—I Oxidation State of Fluorine” where the existence of elemental F 2 on planet Earth is explained and ways to putative polyfluorides are presented.

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