Polymers from triglyceride oils

Güner, F. Seniha; Yaǧcı, Yusuf; Erciyes, A. Tuncer

doi:10.1016/j.progpolymsci.2006.07.001

Cited by 680 publications

(184 citation statements)

References 173 publications

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“…The matrix is synthesized from renewable constituents such as soybean or linseed oil, or from lactic acid (Seniha Güner et al 2006;Å kesson et al 2010). The properties of synthesized matrixes from renewable resources have been explored by researchers and proven to be good alternative to petroleum based matrixes in natural fiber reinforced composites (Å kesson et al 2011;Adekunle et al 2011).…”

Section: Introductionmentioning

confidence: 99%

Performance of biocomposites from surface modified regenerated cellulose fibers and lactic acid thermoset bioresin

et al. 2015

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The effect of surface treatments, silane and alkali, on regenerated cellulose fibers was studied by using the treated fibers as reinforcement in lactic acid thermoset bioresin. The surface treatments were performed to improve the physico-chemical interactions at the fiber-matrix interface. Tensile, flexural and impact tests were used as indicator of the improvement of the interfacial strength. Furthermore, thermal conductivity, viscoelasticity measurements as well as microscopy images were made to characterize the fiber surface treatments and the effect on adhesion to the matrix. The results showed that silane treatment improved the mechanical properties of the composites as the silane molecule acts as link between the cellulose fiber and the resin (the fiber bonds with siloxane bridge while the resin bonds with organofunctional group of the bi-functional silane molecule) which gives molecular continuity in the interphase of the composite. Porosity volume decreased significantly on silane treatment due to improved interface and interlocking between fiber and matrix. Decrease in water absorption and increase in contact angle confirmed the change in the hydrophilicity of the composites. The storage modulus increased when the reinforcements were treated with silane whereas the damping intensity decreased for the same composites indicating a better adhesion between fiber and matrix on silane treatment. Thermogravimetric analysis indicated that the thermal stability of the reinforcement altered after treatments. The resin curing was followed using differential scanning calorimetry and the necessity for post-curing was recommended. Finite element analysis was used to predict the thermal behavior of the composites and a non-destructive resonance analysis was performed to ratify the modulus obtained from tensile testing. The changes were also seen on composites reinforced with alkali treated fiber. Microscopy images confirmed the good adhesion between the silane treated fibers and the resin at the interface.

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Section: Introductionmentioning

confidence: 99%

Performance of biocomposites from surface modified regenerated cellulose fibers and lactic acid thermoset bioresin

et al. 2015

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“…Moreover, life cycle assessment of vegetable oil polyols shows environmental benefits like reduction in the demand of fossil resources and formation of very low greenhouse gas emission [4]. Therefore, the hydroxylated derivatives of vegetable oils are interesting and alternative replacements for petrochemical polyols in the synthesis of PUR materials [5][6][7][8][9].…”

Section: Introductionmentioning

confidence: 99%

Influence of Palm Oil-Based Polyol on the Properties of Flexible Polyurethane Foams

2011

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This paper describes the effect of the modification of polyurethane system with palm oil-based polyol on the cell structure and physical-mechanical properties of polyurethane foams. Flexible polyurethane foams were prepared by substituting a part of petrochemical polyether-polyol with the palm oil polyol. Selected physical-mechanical properties of these foams were examined and compared to the properties of reference foam. The properties such as apparent density, tensile strength, elongation at break, resilience, compressive stress and thermal stability were analyzed. It was found that the modifications of polyurethane formulation with palm oil polyol allow to improve selected properties of final products.

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“…The reaction (1) proceeds signifi cantly slower in comparison with reaction (2), what limits the process. The rate of peracid formation, thereby, the process rate increases by introduction of mineral acid as a catalyst, most often sulphuric(VI) acid or strongly acidic ion exchange resins 25, 35 .…”

Section: The Epoxidation Mechanismmentioning

confidence: 99%

Technological aspects of vegetable oils epoxidation in the presence of ion exchange resins: a review

Milchert

Malarczyk-Matusiak

Musik

2016

Polish Journal of Chemical Technology

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A review paper of the technology basics of vegetable oils epoxidation by means of peracetic or performic acid in the presence of acidic ion exchange resins has been presented. The infl uence of the following parameters: temperature, molar ratio of acetic acid and hydrogen peroxide to ethylenic unsaturation, catalyst loading, stirring intensity and the reaction time on a conversion of ethylenic unsaturation, the relative percentage conversion to oxirane and the iodine number was discussed. Optimal technological parameters, mechanism of epoxidation by carboxylic peracids and the possibilities of catalyst recycling have been also discussed. This review paper shows the application of epoxidized oils.

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Polymers from triglyceride oils

Cited by 680 publications

References 173 publications

Performance of biocomposites from surface modified regenerated cellulose fibers and lactic acid thermoset bioresin

Performance of biocomposites from surface modified regenerated cellulose fibers and lactic acid thermoset bioresin

Influence of Palm Oil-Based Polyol on the Properties of Flexible Polyurethane Foams

Technological aspects of vegetable oils epoxidation in the presence of ion exchange resins: a review

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