Polymerization of m-NH2C6H4COO anions in the intercalation compounds of aluminium hydroxide [LiAl2(OH)6][m-NH2C6H4COO]·nH2O

Study of the In Situ Postintercalative Polymerization of Metanilic Anions Intercalated in NiAl‐Layered Double Hydroxides under a Nitrogen Atmosphere

“…As in the case of other lamellar nanocomposites, atmospheric oxygen was found to play a major role in the polymerization process. [15][16][17] In the present study, we report a new route for preparing PANI/LDH nanocomposites by using pre-intercalated nitrates as the oxidizing agent. In situ chemical oxidative polymerization of metanilic anions (m-NH 2 C 6 H 4 SO 3 -) intercalated in NiAl LDHs under a nitrogen atmosphere has been performed for the first time.…”

Multifunctional Materials: 2D constrained Electronically Conductive Polymer into LDH Matrix

“…In this paper, the incorporation of aniline sulfonic acid (noted as AniS) and its polymerization between Cu 2 Cr(OH) 6 6 octahedra. LDH framework collapses in acidic medium.…”

“…Unfortunately, the intercalative polycondensation of aniline in the pre-swollen LDH materials gives rise to ill-defined biphasic samples. H 2 O hydrotalcitetype compound under mild conditions (heat treament at 90°C for 10 days) by using aniline carboxylic acid [6]. H 2 O hydrotalcitetype compound under mild conditions (heat treament at 90°C for 10 days) by using aniline carboxylic acid [6].…”

“…Recently, it was shown that the polymerization reaction may even occur in the gallery of LiAl 2 (OH) 6 Cl. At first, we choose Cu 2 Cr(OH) 6 Cl . At first, we choose Cu 2 Cr(OH) 6 Cl .…”

"Sintese, caracterização e estudo das propriedades de hidróxidos duplos lamelares intercalados com polímeros condutores"

“…[199][200][201] A reação térmica é muito utilizada na polimerização in situ de monômeros aromáticos, intercalados em matrizes hospedeiras bidimensionais. 39,46,49,157 Nesse tipo de reação, a temperatura de aquecimento, o tempo e a atmosfera devem ser controlados. Altas temperaturas podem levar à degradação do monômero.…”