Polymerizable inorganic–organic hybrid: Syntheses and structures of mono-lacunary Dawson polyoxometalate-based olefin-containing organosilyl derivatives

Isomerization-induced introduction of metal cations into polyoxomolybdate-surfactant hybrid crystals

“…Polyoxometalate (POM) cluster anions are promising candidates as inorganic components to construct functional hybrid materials [6][7][8][9][10][11][12][13]. POMs have been hybridized with structure-directing surfactants [14][15][16] to obtain inorganic-organic hybrid crystals [17][18][19][20][21][22][23][24][25][26][27][28][29][30][31].…”

Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate

“…A search for the corresponding quinone ring system was even less productive, with octamethyl-1,4-cyclohexanedione the only related structure (Hoffmann & Hursthouse, 1976). Structures containing the propyl methacrylate moiety were similarly scarce, with the fullerene derivative 4-(6,9,12,15,18-pentamethyl-C 60 fulleren-1-yl)butyl methacrylate dichloromethane solvate (Matsuo et al, 2009) and a tungsten polyphosphate derivative (Hasegawa et al, 2007) the only hits.…”

Highly Conductive Polymer Electrolytes Constructed from Polymerizable Ionic-Liquid and Inorganic Cluster

“…Several POMs with covalently-grafted polymerizable group have been prepared in a molecularly precise way to form hybrid polymers [38][39][40][41][42][43][44][45][46][47][48][49][50], while the POMs which can be organically modified are very limited to the specific POM species. More versatile but rarely reported method is to utilize polymerizable cations to prepare the hybrid "monomer" with POM anions, which can be polymerized into inorganic-organic hybrid polymers [24,[51][52][53][54].…”