“…Despite the wide variety of polymeric materials, few of them can be used to fabricate polymeric membranes due to limitations such as the preparation of a defect-free thin film, difficult processability, and lack of appropriate mechanical and chemical stability. The gas separation (GS) membranes can be prepared from polymers, including polysulfone (PSf), poly(ether sulfone) (PES), polyurethane (PU), polycarbonate (PC), polyamide (PA), polyimide (PI), poly(ether imide) (PEI), polydimethylsiloxane (PDMS), and polyether- block -amide (PEBA). , PU, being a versatile family of polymers, has been utilized in various fields, such as construction, automobile, healthcare, and fabric industries, due to the versatility of its properties and synthesis methods. − Thermoplastic polyurethane (TPU) is a type of plastic PU that involves a block copolymer consisting of alternating sequences of hard and soft segments . These segments are formed by the reaction of diisocyanates with diols.…”