Polymeric Nanocapsules by Interfacial Miniemulsion Polymerization

Shan, Guorong; Cao, Zhihai

doi:10.1002/9780470922354.ch5

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2012

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“…Interfacial polycondensation is an important polymerization technique, recently used for membrane formation [1] and encapsulation [2]. It involves the extremely rapid reaction of diacid chlorides or bis-chloroformates with diamines.…”

Section: Introductionmentioning

confidence: 99%

Kinetics of Model Reactions for Interfacial Polymerization

et al. 2012

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Abstract:To model the rates of interfacial polycondensations, the rates of reaction of benzoyl chloride and methyl chloroformate with various aliphatic monoamines in acetonitrile were determined at 25 °C. Buffering with picric acid slowed these extremely fast reactions so the rate constants could be determined from the rate of disappearance of picrate ion. The rates of the amine reactions correlated linearly with their Swain-Scott nucleophilicities.

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Section: Introductionmentioning

confidence: 99%