Polyhedral monocarbaborane chemistry

Bullen, Neil J.; Franken, Andreas; Kilner, Colin A.; Teat, Simon J.; Clegg, William; Kennedy, John D.

doi:10.1016/j.jorganchem.2005.02.038

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Heteroboranes1

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Cited by 7 publications

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References 25 publications

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“…Prolonged treatment with FeCl 3 Á 6H 2 O results in oxidative cluster closure of the four pyridine based complexes, which gives the neutral closo ten-vertex monocarbaboranes [1-Ph-6-L-closo-1-CB 9 H 8 ]. 45 The anion [closo-1-CB 9 H 8 -1-COOH-10-I] À has been prepared in four steps from B 10 H 14 . The carboxylic acid is readily converted to the amine [closo-1-CB 9 H 8 -1-NH 2 -10-I] À using the Curtius reaction.…”

Section: Heteroboranesmentioning

confidence: 99%