2004
DOI: 10.1021/ja0398722
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Polyelectrolyte Multilayer as Matrix for Electrochemical Deposition of Gold Clusters:  Toward Super-Hydrophobic Surface

Abstract: This communication describes the use of polyelectrolyte multilayer as a preformed matrix in electrochemical deposition to adjust the morphology of gold clusters, and only the surface covered with dendritic gold clusters shows a super-hydrophobic property, with the contact angle above 150 degrees and the tilt angle less than 1.5 degrees , after the surface further chemisorbed with a self-assembled monolayer of n-dodecanethiol.

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Cited by 630 publications
(357 citation statements)
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“…Different chemical and physical methods for the fabrication of rough surfaces and subsequent application of low-surface-energy coatings on these rough surfaces have been explored, e.g., lithography, [77] sublimation, [78] plasma techniques, [79] self-assembled monolayers, [80] electrochemical methods, [81] electrohydrodynamic/electrospinning techniques, [82] and many more. Electrohydrodynamic techniques proved to be effective methods for the preparation of lotus-leaf-like porous microsphere/nanofiber composite films.…”
Section: Superhydrophobic Surfacesmentioning
confidence: 99%
“…Different chemical and physical methods for the fabrication of rough surfaces and subsequent application of low-surface-energy coatings on these rough surfaces have been explored, e.g., lithography, [77] sublimation, [78] plasma techniques, [79] self-assembled monolayers, [80] electrochemical methods, [81] electrohydrodynamic/electrospinning techniques, [82] and many more. Electrohydrodynamic techniques proved to be effective methods for the preparation of lotus-leaf-like porous microsphere/nanofiber composite films.…”
Section: Superhydrophobic Surfacesmentioning
confidence: 99%
“…superhydrophobic surfaces where the contact angle is larger than 150 • ) are mostly used in self-cleaning surfaces [2], tunable lenses [3], micro-fluidic systems [4] and non-adhesive coating [5,6]. Since the last two decades, the wetting phenomena on superhydrophobic surface has become a subject of fundamental research in physics [7][8][9], chemistry [10], biology [11,12] and materials science [13,14]. In material science, many metallic superhydrophobic surfaces are mostly used as anticorrosive surfaces.…”
Section: Introductionmentioning
confidence: 99%
“…The hierarchical structure for increased roughness provides an efficient strategy to increase the liquid-air contacting area. 40 In addition, the modification of the lowsurface-energy coating of HS(CH 2 ) 11 CH 3 is favorable for reducing y 1 . Hence, the rough gold aggregates and HS(CH 2 ) 11 CH 3 coating should contribute to superhydrophobicity.…”
Section: Resultsmentioning
confidence: 99%