Polybenzimidazoles (PBIs) and state-of-the-art PBI hollow fiber membranes for water, organic solvent and gas separations: a review

Chung, Tai‐Shung; Weber, Martin; Chung, Tai‐Shung

doi:10.1039/d2ta00422d

Cited by 51 publications

(24 citation statements)

References 232 publications

(400 reference statements)

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“…They are cheap, commercially available, scalable, possess defect-free nature, and have promising separation performance. Polymers such as PES [ 29 , 158 , 171 , 172 , 183 , 398 , 399 , 400 , 401 , 402 , 403 , 404 , 405 , 406 ], PSF [ 28 , 30 , 36 , 407 , 408 , 409 , 410 , 411 , 412 , 413 , 414 , 415 , 416 , 417 , 418 , 419 ], polyimide [ 110 , 420 , 421 , 422 , 423 , 424 , 425 , 426 , 427 ], PAN [ 34 , 70 , 162 , 170 , 428 , 429 , 430 , 431 ], and PBI [ 180 , 432 , 433 ] are the common polymers used to fabricate hollow fiber membranes in vari...…”

Section: Applications Of Hollow Fiber Membranesmentioning

confidence: 99%

“…Polymers such as PES [ 29 , 158 , 171 , 172 , 183 , 398 , 399 , 400 , 401 , 402 , 403 , 404 , 405 , 406 ], PSF [ 28 , 30 , 36 , 407 , 408 , 409 , 410 , 411 , 412 , 413 , 414 , 415 , 416 , 417 , 418 , 419 ], polyimide [ 110 , 420 , 421 , 422 , 423 , 424 , 425 , 426 , 427 ], PAN [ 34 , 70 , 162 , 170 , 428 , 429 , 430 , 431 ], and PBI [ 180 , 432 , 433 ] are the common polymers used to fabricate hollow fiber membranes in various configurations. Notably, PBI has been widely reported for effective H 2 purification at elevated temper...…”

Section: Applications Of Hollow Fiber Membranesmentioning

confidence: 99%

“…Notably, PBI has been widely reported for effective H 2 purification at elevated temperatures benefiting from its rigid polymer chains, high thermal properties, and diffusivity-based selectivity at a temperature above 150 °C [ 433 ]. In addition to the common application such as CO 2 capture [ 30 , 34 , 66 , 70 , 110 , 158 , 162 , 170 , 171 , 172 , 399 , 400 , 407 , 408 , 409 , 420 , 422 , 423 , 424 , 425 , 429 , 431 , 434 , 435 , 436 , 437 ], air purification [ 29 , 398 , 401 , 402 , 403 , 410 , 411 , 421 , 426 , 438 ], and hydrogen separation [ 28 , 36 , 183 , 404 , 427 , 432 , 433 , 439 , 440 ], polymeric-based hollow fiber membranes also received attention to be used for industrial applications, e.g., hydrocarbon [ 425 ,...…”

Section: Applications Of Hollow Fiber Membranesmentioning

confidence: 99%

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State-of-the-Art Organic- and Inorganic-Based Hollow Fiber Membranes in Liquid and Gas Applications: Looking Back and Beyond

Lau

Soh

et al. 2022

Membranes

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The aggravation of environmental problems such as water scarcity and air pollution has called upon the need for a sustainable solution globally. Membrane technology, owing to its simplicity, sustainability, and cost-effectiveness, has emerged as one of the favorable technologies for water and air purification. Among all of the membrane configurations, hollow fiber membranes hold promise due to their outstanding packing density and ease of module assembly. Herein, this review systematically outlines the fundamentals of hollow fiber membranes, which comprise the structural analyses and phase inversion mechanism. Furthermore, illustrations of the latest advances in the fabrication of organic, inorganic, and composite hollow fiber membranes are presented. Key findings on the utilization of hollow fiber membranes in microfiltration (MF), nanofiltration (NF), reverse osmosis (RO), forward osmosis (FO), pervaporation, gas and vapor separation, membrane distillation, and membrane contactor are also reported. Moreover, the applications in nuclear waste treatment and biomedical fields such as hemodialysis and drug delivery are emphasized. Subsequently, the emerging R&D areas, precisely on green fabrication and modification techniques as well as sustainable materials for hollow fiber membranes, are highlighted. Last but not least, this review offers invigorating perspectives on the future directions for the design of next-generation hollow fiber membranes for various applications. As such, the comprehensive and critical insights gained in this review are anticipated to provide a new research doorway to stimulate the future development and optimization of hollow fiber membranes.

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Section: Applications Of Hollow Fiber Membranesmentioning

confidence: 99%

Section: Applications Of Hollow Fiber Membranesmentioning

confidence: 99%

Section: Applications Of Hollow Fiber Membranesmentioning

confidence: 99%

See 1 more Smart Citation

State-of-the-Art Organic- and Inorganic-Based Hollow Fiber Membranes in Liquid and Gas Applications: Looking Back and Beyond

Lau

Soh

et al. 2022

Membranes

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“…HF OSN membranes can now achieve higher output and product purity at the same production cost. However, preparation difficulties and scale-up effects have limited the commercial application of HF OSN membranes [ 73 , 87 ], and there are still no commercially available HF OSN membranes [ 15 , 17 , 30 , 31 , 126 ]. In the following, a brief overview of the status quo, challenges, and future outlook of HF OSN membrane development is presented.…”

Section: Status Quo Challenges and Outlook Of Hf Osn Technologiesmentioning

confidence: 99%

Hollow Fiber Membrane for Organic Solvent Nanofiltration: A Mini Review

Liu

Wang

et al. 2022

Membranes

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Organic solvents take up 80% of the total chemicals used in pharmaceutical and related industries, while their reuse rate is less than 50%. Traditional solvent treatment methods such as distillation and evaporation have many disadvantages such as high cost, environmental unfriendliness, and difficulty in recovering heat-sensitive, high-value molecules. Organic solvent nanofiltration (OSN) has been a prevalent research topic for the separation and purification of organic solvent systems since the beginning of this century with the benefits of no-phase change, high operational flexibility, low cost, as well as environmental friendliness. Especially, hollow fiber (HF) OSN membranes have gained a lot of attention due to their high packing density and easy scale-up as compared with flat-sheet OSN membranes. This paper critically reviewed the recent research progress in the preparation of HF OSN membranes with high performance, including different materials, preparation methods, and modification treatments. This paper also predicts the future direction of HF OSN membrane development.

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“…Besides hydrogen separation, porous membranes with precisely controlled nanostructure can be applied to other gas or solvent separation/capture processes. [53][54][55] In addition to membrane synthesis, boehmite nanoparticles can be used in other disciplines, 56 including chemistry, petroleum, medicine, energy, and the environment (Fig. S2 †).…”

Section: Introductionmentioning

confidence: 99%

Synthesis of size-controlled boehmite sols: application in high-performance hydrogen-selective ceramic membranes

et al. 2022

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Polybenzimidazoles (PBIs) and state-of-the-art PBI hollow fiber membranes for water, organic solvent and gas separations: a review

Abstract: As an attractive candidate material, polybenzimidazole (PBI) has been explored for fabricating hollow fiber membranes (HFMs) employed in liquid and gas separations since 1970s. Some of its membranes have achieved...

Cited by 51 publications

References 232 publications

State-of-the-Art Organic- and Inorganic-Based Hollow Fiber Membranes in Liquid and Gas Applications: Looking Back and Beyond

State-of-the-Art Organic- and Inorganic-Based Hollow Fiber Membranes in Liquid and Gas Applications: Looking Back and Beyond

Hollow Fiber Membrane for Organic Solvent Nanofiltration: A Mini Review

Synthesis of size-controlled boehmite sols: application in high-performance hydrogen-selective ceramic membranes

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