Polyacetylene‐Based Asymmetric Bicyclic Polymer by Blocking‐Cyclization Technique
Cuihong Ma,
Hao Wang,
Ruyi Sun
et al.
Abstract:A rare asymmetric bicyclic polymer containing different length of conjugated polyacetylene segments was synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique. The size of each single ring differed from each other, and the unique cyclic polymer topology was controlled by adjusting the feed ratio of monofunctional monomer to catalyst. The topological difference between linear and bicyclic polymers was confirmed by several techniques, and the visualized morphology of asymmetric bic… Show more
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