Poly[[[triaquaerbium(III)]-μ<sub>3</sub>-succinato] chloride dihydrate]

Nika, Wassiliki; Pantenburg, Ingo; Meyer, Gerd

doi:10.1107/s1600536804032635

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Cited by 5 publications

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“…1). The bond lengths and angles compare well with those found in poly [[[triaquaerbium(III)]-3 -succinato] chloride dihydrate] (Nika et al, 2005).…”

Section: Commentsupporting

confidence: 73%

Poly[diaquadi-μ₆-succinato-μ₅-succinato-dierbium(III)]

Dong¹,

Cui²,

Lin

2006

Acta Cryst E

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“…1). The bond lengths and angles compare well with those found in poly [[[triaquaerbium(III)]-3 -succinato] chloride dihydrate] (Nika et al, 2005).…”

Section: Commentsupporting

confidence: 73%

Poly[diaquadi-μ₆-succinato-μ₅-succinato-dierbium(III)]

Dong¹,

Cui²,

Lin

2006

Acta Cryst E

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Three-dimensional ionic frameworks built up from La (III) and Ce (III) succinates

Rahahlia

Benmerad

Guehria-Laïdoudî

et al. 2007

Journal of Molecular Structure

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Syntheses, Crystal Structures, and Magnetic Properties of [Ln^III₂(Succinate)₃(H₂O)₂]·0.5H₂O [Ln = Pr, Nd, Sm, Eu, Gd, and Dy] Polymeric Networks: Unusual Ferromagnetic Coupling in Gd Derivative

et al. 2006

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Lanthanide-organic coordination polymeric networks of [Ln(III)2(suc)3(H2O)2].0.5H2O [suc = succinate dianion, Ln = Pr (1), Nd (2), Sm (3), Eu (4), Gd (5), and Dy (6)] have been synthesized and characterized by single-crystal X-ray diffraction analyses. The structural determination reveals that complexes are isomorphous, all crystallizing in monoclinic system, space group I2/a(.) The complexes possess a 3D architecture with Ln ion in a nine-coordination geometry attained by eight oxygen atoms from succinate and one oxygen atom from an aqua ligand. Low-temperature magnetic study indicates that ferromagnetic interaction is present in case of Gd(III) and Dy(III). Antiferromagnetic interaction is observed for the rest of the complexes. Density functional theory calculations are performed which support the existence of a superexchange ferromagnetic coupling in Gd(III) ions, whereas classical crystal field model has been applied to study the complexes 1, 2, 3, and 6.

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Poly[[[triaquaerbium(III)]-μ₃-succinato] chloride dihydrate]

Abstract: Key indicatorsSingle-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.020 wR factor = 0.051 Data-to-parameter ratio = 14.7For details of how these key indicators were automatically derived from the article, see

Cited by 5 publications

References 4 publications

Poly[diaquadi-μ₆-succinato-μ₅-succinato-dierbium(III)]

Poly[diaquadi-μ₆-succinato-μ₅-succinato-dierbium(III)]

Three-dimensional ionic frameworks built up from La (III) and Ce (III) succinates

Syntheses, Crystal Structures, and Magnetic Properties of [Ln^III₂(Succinate)₃(H₂O)₂]·0.5H₂O [Ln = Pr, Nd, Sm, Eu, Gd, and Dy] Polymeric Networks: Unusual Ferromagnetic Coupling in Gd Derivative

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Poly[[[triaquaerbium(III)]-μ3-succinato] chloride dihydrate]

Abstract: Key indicatorsSingle-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.020 wR factor = 0.051 Data-to-parameter ratio = 14.7For details of how these key indicators were automatically derived from the article, see

Cited by 5 publications

References 4 publications

Poly[diaquadi-μ6-succinato-μ5-succinato-dierbium(III)]

Poly[diaquadi-μ6-succinato-μ5-succinato-dierbium(III)]

Three-dimensional ionic frameworks built up from La (III) and Ce (III) succinates

Syntheses, Crystal Structures, and Magnetic Properties of [LnIII2(Succinate)3(H2O)2]·0.5H2O [Ln = Pr, Nd, Sm, Eu, Gd, and Dy] Polymeric Networks: Unusual Ferromagnetic Coupling in Gd Derivative

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Poly[[[triaquaerbium(III)]-μ₃-succinato] chloride dihydrate]

Poly[diaquadi-μ₆-succinato-μ₅-succinato-dierbium(III)]

Poly[diaquadi-μ₆-succinato-μ₅-succinato-dierbium(III)]

Syntheses, Crystal Structures, and Magnetic Properties of [Ln^III₂(Succinate)₃(H₂O)₂]·0.5H₂O [Ln = Pr, Nd, Sm, Eu, Gd, and Dy] Polymeric Networks: Unusual Ferromagnetic Coupling in Gd Derivative