Poly(trialkylsilyl methacrylate)s: A family of hydrolysable polymers with tuneable erosion profiles

Bressy, Christine; Nguyen, Minh Ngoc; Tanguy, Brigitte; Ngo, Van Giang; Margaillan, André

doi:10.1016/j.polymdegradstab.2010.03.017

Cited by 52 publications

(35 citation statements)

References 20 publications

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“…Despite the importance of copolymerizations via the RDRP, fundamental copolymerization kinetic studies on such functional monomers mentioned above have not been investigated thoroughly. In fact, detailed copolymerization kinetics provides significant information on the reactivities of monomers and activated species, and ultimately on the copolymer composition and chain structure which can affect the final properties . Rather, we often refer the kinetics studies conducted by conventional free radical polymerization to predict the reactivities of reactants and structure and properties of copolymers synthesized via the RDRPs .…”

Section: Introductionmentioning

confidence: 99%

Copolymerization Kinetics of a Simple Methacrylate and Functional Comonomers Via Cu(0)‐mediated Reversible Deactivation Radical Polymerization

Kim

Choe

Son

et al. 2019

Bulletin Korean Chem Soc

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We demonstrate thorough studies on copolymerization of methyl methacrylate (MMA) with widely used commercially available functional monomers, allyl methacrylate (AMA), 2‐hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA) and N‐isopropyl acrylamide (NIPAM), via Cu(0)‐mediated reversible deactivation radical polymerization (Cu(0)‐RDRP), and further compared to copolymerization kinetics of MMA with ethyl methacrylate (EMA). The apparent propagation rate constants and induction periods of the copolymerizations were estimated to reveal the effect of monomer type to copolymerization kinetics. Further studies show that MMA/AMA and MMA/HEMA exhibit relatively random distributions of functional monomer units in copolymer chains; however, MMA/NIPAM does not as activated MMA and NIPAM prefer homopolymerization and crosspolymerization, respectively. Copolymerization conditions for all pairs show less reactivity differences compared to the cases of other radical‐based polymerizations, highlighting the importance of polymerization methods and conditions to control copolymer microstructure, and emphasizing the significance of deeper understanding in RDRPs.

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Section: Introductionmentioning

confidence: 99%

Copolymerization Kinetics of a Simple Methacrylate and Functional Comonomers Via Cu(0)‐mediated Reversible Deactivation Radical Polymerization

Kim

Choe

Son

et al. 2019

Bulletin Korean Chem Soc

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“…S S * BzMA [161] MMA [162] PEGMA [163] 302 [164] 301 [165] 312 [166] 396 [167] MA [168] PFPVB [169] PVS [169] St [132,162] 359 [170] St [171] BA [122] MMA/BDSMA [172] (MAA/TPMMA) [173] (MAA/293) [173] DEGMA/PEGMA [174] tBMA/DMAEMA/290 [175] MMA/LMA [163] 396-b-PEGMA [167] St/AcS [176] 4VP/EGDMA [177] (St-b-DMAEMA) [171] BzMA-b-HPMAm [161] DEGMA/PEGMA-b-DMAPMAm [174] PEGMA-b-MMA [163] LMA/MMA-b-PEGMA [163] 12 S S CN D* [178] MMA [178][179][180][181][182][183][184] PEGMA [111,185] GMA [186] 289 [186,187] 297 [188] 324 [189] 453 [190] iPOx [191] St [132,…”

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confidence: 99%

Living Radical Polymerization by the RAFT Process – A Third Update

2012

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This paper provides a third update to the review of reversible deactivation radical polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC(¼S)SR) by a mechanism of reversible addition-fragmentation chain transfer ( Chem. 2009Chem. , 62, 1402. This review cites over 700 publications that appeared during the period mid 2009 to early 2012 covering various aspects of RAFT polymerization which include reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses, and a diverse range of applications. This period has witnessed further significant developments, particularly in the areas of novel RAFT agents, techniques for end-group transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

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“…Copolymers based on hydrolysable poly(tert-butyldimethylsilyl methacrylate), Pt-BDMSMA and poly(methyl methacrylate) (PMMA) were synthesized and studied to show that they can be used as polymer binders in self-polishing antifouling coatings. Nevertheless, a major drawback of the paint films made from these copolymers is that they are quite brittle due to their high glass transition temperatures (Tg, PMMA = 100-105 ºC, Tg, Pt-BDMSMA = 135-142 ºC) [5,6]. This causes an additional utilization of plasticizers, which results in cost increases and deterioration of certain physico-mechanical properties of paint films.…”

Section: Synthesis and Characterization Of Random And Block-random DImentioning

confidence: 99%

“…In our previous works [4][5][6], we indicated that a replacement of tin in organotin compounds-based self-polishing copolymers by silicon, a more eco-friendly element, still maintained…”

Section: Introductionmentioning

confidence: 96%

Synthesis and Characterization of Random and Block-Random Diblock Silylated Terpolymers via RAFT Polymerization

Nguyen¹,

Pham²,

Le³

et al. 2018

Asian J. Chem.

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Well-defined random and block-random diblock terpolymers consisting of methyl methacrylate (MMA), butyl acrylate (BA) and tertbutyldimethylsilyl methacrylate (t-BDMSMA) were successfully synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization using 2-cyanoprop-2-yl-dithiobenzoate (CPDB) as RAFT agent.1 H NMR and GPC analyses indicated the formation of random terpolymers [P(MMA-co-BA-co-t-BDMSMA)] and block-random diblock terpolymers [(PMMA-b-P(BA-co-t-BDMSMA) and Pt-BDMSMA-b-P(BA-co-MMA)] with good control of terpolymer composition, molecular weights and molecular weight distributions (Ð < 1.20). Thermal analysis results showed that the random terpolymers exhibited only one glass transition temperature (Tg) which depends on the terpolymer composition. The (PMMA-b-P(BA-co-t-BDMSMA) block-random diblock terpolymer showed two Tg that can be attributed to two blocks of terpolymer. Meanwhile, Pt-BDMSMA-b-P(BA-co-MMA) block-random diblock terpolymer exhibited only one Tg value, which is probably due to a low proportion of Pt-BDMSMA block present in the terpolymer.

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Poly(trialkylsilyl methacrylate)s: A family of hydrolysable polymers with tuneable erosion profiles

Cited by 52 publications

References 20 publications

Copolymerization Kinetics of a Simple Methacrylate and Functional Comonomers Via Cu(0)‐mediated Reversible Deactivation Radical Polymerization

Copolymerization Kinetics of a Simple Methacrylate and Functional Comonomers Via Cu(0)‐mediated Reversible Deactivation Radical Polymerization

Living Radical Polymerization by the RAFT Process – A Third Update

Synthesis and Characterization of Random and Block-Random Diblock Silylated Terpolymers via RAFT Polymerization

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