Poly(ether)s derived from oxa-Michael polymerization - A comprehensive review

Abstract

Poly(ether)s represent an important class of polymers and are typically formed by ring-opening polymerization, Williamson ether synthesis or self-condensation of alcohols. The oxa-Michael reaction presents another method to form poly(ether)s with additional functional groups in the polymer backbone starting from di- or triols and electron deficient olefins such as acrylates, sulfones or acrylamides. However, research on oxa-Michael polymerization is still limited. Herein, we outline the principles of the oxa-Michael polymerization and focus on the synthesis and preparation of poly(ether-sulfone)s, poly(ether-ester)s, poly(ether)s and poly(ether-amide)s. Further, challenges as well as future perspectives of the oxa-Michael polymerization are discussed.