Poly[[diaquabis(μ-3,3′,5,5′-tetramethyl-4,4′-bipyrazole-κ2N:N′)cobalt(II)] dinitrate]

This Perspective summarises the chemistry of the pyrazole ring, and reviews the metal coordination modes adopted by 1H-pyrazoles and their anions. Pyrazolide anions are probably the most versatile ligands in coordination chemistry, with 20 different terminal or bridging coordination modes having been identified so far. Metal cluster compounds supported by pyrazolido ligation are surveyed, concentrating on those reported during the past ten years. Highlights include the wide structural diversity in apparently simple main group pyrazolides; luminescence and charge-transfer complexes in coinage metal pyrazolide clusters; the use of robust metal pyrazolide clusters to construct liquid crystals, supramolecular materials and metal-organic frameworks; and supramolecular complexes formed by pyrazolide-supported metallacrowns.

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Modular construction of 3D coordination frameworks incorporating SiF62− links: Accessing the significance of [M(pyrazole)4{SiF6}] synthon

Ponomarova

Komarchuk

Boldog

et al. 2013

CrystEngComm

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Poly[[diaquabis(μ-3,3′,5,5′-tetramethyl-4,4′-bipyrazole-κ²N:N′)cobalt(II)] dinitrate]

Abstract: Key indicatorsSingle-crystal X-ray study T = 295 K Mean (C-C) = 0.006 Å R factor = 0.051 wR factor = 0.169 Data-to-parameter ratio = 17.9For details of how these key indicators were automatically derived from the article, see

Cited by 3 publications

References 13 publications

Coordination polymers and metal–organic frameworks based on poly(pyrazole)-containing ligands

Coordination polymers and metal–organic frameworks based on poly(pyrazole)-containing ligands

Pyrazoles and pyrazolides—flexible synthons in self-assembly

Modular construction of 3D coordination frameworks incorporating SiF62− links: Accessing the significance of [M(pyrazole)4{SiF6}] synthon

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