Poly[[diaqua[μ5-(R,S)-2-({2-[(1,2-dicarboxylatoethyl)amino]ethyl}amino)butanedioato]cobaltate(III)sodium] dihydrate]

Trunova, Elena; Dudko, Anatolij V.; Makotryk, Tamara; Osadcha, Olena V.; Pekhnyo, V. I.; Shovkova, Ganna V.

doi:10.1107/s160053681104013x

Cited by 4 publications

(2 citation statements)

References 11 publications

(15 reference statements)

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“…7, a, b). Therefore, upon entering a living cell, these substances will be perceived by them not as alien elements, but as «their own», which will ensure their biogenic compatibility and accordingly, high absorption [51][52][53][54]. Almost all microelements form fairly stable complexes with the given ligands, while the form of the complexes strongly depends on the pH of the solution or soil.…”

Section: Inorganic Chemistrymentioning

confidence: 99%

The Role of Chelate Coordination Compounds of Biogenic Metals in the Vital Activity of Plants

Trunova¹

2023

Ukr. Chem. Journ.

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The review article discusses the main issues of creating and using modern chelated microfertilizers based on trace elements in agricultural production. Issues of the role of microelements in the vital activity of living organisms and methods of overcoming the lack of microelements in plants are highlighted. An overview of coordination compounds of 3d-metals (Fe, Mn, Zn, Cu, Co, Ni, Mo) with different classes of complexons, features of their structure and properties is presented. It contains relevant material on the use of microelement complexes for the creation of modern chelated fertilizers. Attention is paid to the use of trace elements complexonates in areas contaminated with radionuclides (137Сs, 90Sr).

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Section: Inorganic Chemistrymentioning

confidence: 99%

The Role of Chelate Coordination Compounds of Biogenic Metals in the Vital Activity of Plants

Trunova¹

2023

Ukr. Chem. Journ.

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“…Ці роботи стали основою для розвитку в Інституті біонеорганічної хімії, у тому числі координаційних сполук із різними класами біолігандів (амінокіслоти, модифіковані комплексони, похідні тіосечовини, гідразонів тощо). Продовжуючи вказаний напрямок досліджень, у відділі гетерофазного синтезу неорганічних сполук та матеріалів синтезовано та систематично досліджено моно-, гетерометалічні та різнолігандні комплекси 3-d-металів з етилендиаміндіянтарною кислотою у водних розчинах і твердому стані, вивчено їхні властивості (фізико-і фотохімічні, біологічно активні) і структурні особливості [92][93][94][95]. Встановлено основні закономірності формування комплексів заданого складу з прогнозованими властивостями [96].…”

Section: початок огляду в № 11 за 2021 рікunclassified

DEVELOPMENT OF RESEARCH OF CHEMISTRY OF COORDINATION COMPOUNDS IN V.I. VERNADSKY INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY NAS OF UKRAINE: FROM THE 30'S TWENTIETH CENTURY (part 2)

2022

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The review considers the main stages of development of the chemistry of coordination compounds at the Institute of General and Inorganic Chemistry. VI Vernadsky National Academy of Sciences of Ukraine on the occasion of the 90th anniversary of its founding. An overview of complex compounds of p, d, f-metals with different classes of ligands (inorganic and organic), features of their synthesis, study of the structure and properties of the obtained compounds, contains current material on the use of synthesized complexes to create functional materials for different purposes. Methods of synthesis have been developed, dozens of new coordination compounds with derivatives of hydrazones, amines, azomethanes, and thiosemicarbazones have been synthesized and isolated in the individual state. Their composition, structure and physicochemical properties are determined. The general regularities that take place in the process of complexation of metals with ligands, as well as factors influencing the composition, structure and physicochemical properties of the obtained coordination compounds are established. For the long history of the Institute has accumulated a huge amount of material on the problems of modern coordination chemistry. Significant research in this area belongs to Ukrainian scientists who have worked long and fruitfully at the Institute: A.K. Babko, К.B. Yatsimirsky, Ya.A. Fialkov, I.A. Sheka, S.V. Volkov, N.A. Kostromina, and who created scientific schools, known not only in Ukraine but also abroad. To date, the attention of scientists of the Institute has shifted from classical monomeric to bigeteronuclear, polynuclear, multiligand complexes, which is primarily due to intensive research of new functional materials: optical and magnetic, biologically active substances, as well as effective adsorbents, chemical sensors, catalysts, catalysts, catalysts and biochemical processes.

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Crystal structure of a novel cobalt(II) complex with ethylenediaminedisuccinic acid

2018

VKhKhT

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Poly[[diaqua[μ₅-(R,S)-2-({2-[(1,2-dicarboxylatoethyl)amino]ethyl}amino)butanedioato]cobaltate(III)sodium] dihydrate]

Cited by 4 publications

References 11 publications

The Role of Chelate Coordination Compounds of Biogenic Metals in the Vital Activity of Plants

The Role of Chelate Coordination Compounds of Biogenic Metals in the Vital Activity of Plants

DEVELOPMENT OF RESEARCH OF CHEMISTRY OF COORDINATION COMPOUNDS IN V.I. VERNADSKY INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY NAS OF UKRAINE: FROM THE 30'S TWENTIETH CENTURY (part 2)

Crystal structure of a novel cobalt(II) complex with ethylenediaminedisuccinic acid

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