2004
DOI: 10.1063/1.1786575
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Polaron-exciton model of resonance energy transfer

Abstract: It is shown that Förster's expression for the electronic energy transfer rate can be recast in a form predicted for exciton motion that interacts strongly with molecular vibrations. Using a simple model based on the Kennard-Stepanov theory, Förster's expression for the spectral overlap is shown to be of a thermally activated form, as obtained previously by multiphonon theory. In contrast, the high-frequency internal vibrations contribute a factor which results from tunneling through a potential barrier between… Show more

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Cited by 13 publications
(11 citation statements)
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References 28 publications
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“…Indeed, the Huang‐Rhys factor can be related to the change in the equilibrium geometries between the ground state and the relaxed singlet‐excited state (Δ Q ), by way of Equation (3) 40 …”
Section: Resultsmentioning
confidence: 99%
“…Indeed, the Huang‐Rhys factor can be related to the change in the equilibrium geometries between the ground state and the relaxed singlet‐excited state (Δ Q ), by way of Equation (3) 40 …”
Section: Resultsmentioning
confidence: 99%
“…[9,59]). It was recently perceived [60] that incoherent Förster energy transfer processes and thermally activated transport by self-trapped excitonic polarons are closely related. Efforts are still required to explicitly demonstrate this idea on clusters of antenna complexes and on intact photosynthetic membranes.…”
Section: Discussionmentioning
confidence: 99%
“…3). A theory first proposed by Kazachenko [24] then gives a relationship between the Stokes shift ES and the width σ of the Gaussian absorption / emission bands [24,25]:…”
Section: Fig 1 Schematic Of Experimental Setup For Edge Fl Detectionmentioning
confidence: 99%