1953
DOI: 10.1021/ac60078a043
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Polarographic Characteristics of Metallic Cations in Acetate Media

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1954
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Cited by 29 publications
(3 citation statements)
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“…Electron changes were calculated by accepted procedures described in the literature (4, 7) and the results are given in Table I. The 3-electron change for antimony is believed to be from Sb+3 to the amalgam, which agrees with the work of Desesa (8) and Lingane (9). The electron change for indium shows the reaction to be In+3 to In0.…”
Section: Resultssupporting
confidence: 64%
“…Electron changes were calculated by accepted procedures described in the literature (4, 7) and the results are given in Table I. The 3-electron change for antimony is believed to be from Sb+3 to the amalgam, which agrees with the work of Desesa (8) and Lingane (9). The electron change for indium shows the reaction to be In+3 to In0.…”
Section: Resultssupporting
confidence: 64%
“…With most of the metal driers the reaction at the dropping mercury electrode is thought to be associated with the reduction of the metal complex to the metallic state (2).…”
Section: Discussionmentioning
confidence: 99%
“…The molybdosilicic acid complex present in an acetic acid-sodium acetate buffer of pH 3.5 produced a single, double, and triple wave with increasing concentration and gave half-wave potentials in the neighborhood of -0.2, -0.5, and -0.55 volt vs. saturated calomel electrode. These studies were not directty applicable to analytical determinations because the polarograms were made on solutions prepared by dissolving the solid heteropoly acid directly in the supporting electrolyte, whereas in an analytical procedure the heteropoly acid would be formed in solution using excess molybdate which is reducible in an acetate buffer (8). The study by Strickland (20), comparing the polarographic behavior of the a and 0 forms of molybdosilicic acid in 0.1V potassium sulfate at a pH of approxi-mately 3.5, was encouraging.…”
mentioning
confidence: 99%