“…Recently, nanocrystalline CoO has been reported as a photocatalyst for water splitting by visible-light irradiation [16], and both CoO and Co 3 O 4 have potential applications in devices such as battery electrodes [17], gas sensors [15,[18][19][20], solar-selective absorbers [21] and spintronic devices through the formation of exchange bias layers [22]. Epitaxial thin films or layers of these cobalt oxides have been grown by several methods, including PLD [23][24][25], molecular beam epitaxy [26][27][28][29], atomic layer deposition [30][31][32], chemical vapor deposition [33], sol-gel [34], thermal evaporation [35], and surface oxidation of metallic cobalt [36,37]. However, the previously reported epitaxial growth requires relatively high substrate temperature of at least 138 • C or post-annealing for oriented crystallization [30].…”