Motivated by recent interest in low dimensional arrays of atoms, we experimentally investigated the way cold collisional processes are affected by the geometry of the considered atomic sample. More specifically, we studied the case of photoassociative ionization (PAI) both in a storage ring where collision is more unidirectional in character and in a trap with clear undefinition of collision axis. First, creating a ring shaped trap (atomotron) we investigated two-color PAI dependence with intensity and polarization of a probing laser. The intensity dependence of the PAI rate was also measured in a magneto-optical trap presenting equivalent temperature and density conditions. Indeed, the results show that in the ring trap, the value of the PAI rate constant is much lower and does not show evidences of saturation, unlike in the case of the 3D-MOT. Cold atomic collisions in storage ring may represent new possibilities for study.© 2012 Elsevier B.V. All rights reserved.The field of cold atomic collisions followed the overall development of cold atomic physics in general [1]. The area gave rise to an exciting collection of scientific opportunities and still provides steam for future achievements. Study of novel cold collision geometries may contribute to a better understanding of reaction dynamics, possibly pushing back the frontiers of quantum chemistry.One of the many questions that motivated the investigation of cold collisions is how an optical field can modify the outcome of a collisional encounter. A natural environment for observation of such an effect is an atomic trap, like the magneto-optical trap (MOT) for instance. In such a system there is no preferable axis of collision and only average effects can be measured. Experiments involving atomic beams decelerated by radiation pressure, yet are alternatives to this situation [2]. However, for collisions in the sub-millikelvin temperature regime, the atomic beam density is usually much below the one you can reach in a MOT. Recently though, our research group has advised a new way to study cold collisions, producing a ring shaped trap (atomotron) [3], where atomic encounters preferably take place along one single direction. This trap actually works close to a continuous atomic beam of cold atoms with the tangential direction as the preferable collisional axis.Concerning cold collision processes, Photoassociative Ionization (PAI) [4] probably figures amongst the most important ones. PAI is a two step molecular formation resulting in an ionized dimer. PAI was the first measured collisional process observed between cooled atoms [5] and even though it already has been intensively explored [1], open questions still remain, specially related to the relative reaction rates measured in traps and in atomic beams. Due to technical difficulties, temperatures in both systems were never compatible and a fair comparison was never performed for sodium.Conventional associative ionization proceeds in two steps: excitation of isolated atoms followed by molecular autoionization wh...