It
remains a challenge to directly print arbitrary three-dimensional
shapes that exhibit structural colors at the micrometer scale. Woodpile
photonic crystals (WPCs) fabricated via two-photon
lithography (TPL) are elementary building blocks to produce 3D geometries
that generate structural colors due to their ability to exhibit either
omnidirectional or anisotropic photonic stop bands. However, existing
approaches produce structural colors on WPCs when illuminating from
the top, requiring print resolutions beyond the limit of commercial
TPL, which necessitates postprocessing techniques. Here, we devised
a strategy to support high-order photonic cavity modes upon side illumination
on WPCs that surprisingly generate prominent reflectance peaks in
the visible spectrum. Based on that, we demonstrate one-step printing
of 3D photonic structural colors without requiring postprocessing
or subwavelength features. Vivid colors with reflectance peaks exhibiting
a full width at half-maximum of ∼25 nm, a maximum reflectance
of 50%, a gamut of ∼85% of sRGB, and large viewing angles were
achieved. In addition, we also demonstrated voxel-level manipulation
and control of colors in arbitrary-shaped 3D objects constituted with
WPCs as unit cells, which has potential for applications in dynamic
color displays, colorimetric sensing, anti-counterfeiting, and light–matter
interaction platforms.