Abstract. We have measured the alignment and orientation parameters of the 2F°/2 and 2F° n states of At + formed in the two-electron process; He + + Ar--, He(ls 2) + Ar + (3 p44p').These have been measured at a collision energy of 0.25 keV/amu and for scattering angles ranging from 0.94 ° to 3.75 ° . First, by comparing the orientation parameter for the Ar + [(3p411D]4p ' 2F°/j and the Ar + [(3 p4 [1D] 4 p' 2F°/j states, we have experimentally determined the importance of the spin-dependent interactions for the present collision system, by testing the Percival-Seaton hypothesis of spin independence. If the Percival-Seaton hypothesis holds for this system, the orientation parameter should be J-independent. Secondly, the magnitude of the orientation parameter can be interpreted as resulting from the collective circulation of the unexcited 3p 4 electrons and the excited 4p electron. The direction of this collective circulation is compared to the propensity rule for colliding di-atom systems.