Poison or Promoter? Investigating the Dual-Role of Carbon Monoxide in Pincer-Iridium-Based Alkane Dehydrogenation Systems via Operando Diffuse Reflectance Infrared Fourier Transform Spectroscopy
Abstract:<p>Pincer-ligated iridium
complexes of the <a>form [Ir(<sup>R4</sup>PCP)L] (<sup>R4</sup>PCP
= κ<sup>3</sup>-C<sub>6</sub>H<sub>3</sub>-2,6-(XPR<sub>2</sub>)<sub>2</sub>; X
= CH<sub>2</sub>, O; R = <i>t</i>Bu, <i>i</i>Pr) </a>have previously been shown
competent for acceptorless alkane dehydrogenation when supported on silica. It
was observed by post-catalysis solid-state NM… Show more
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