“…2,7 Halides of actinides have been synthesized in the past. 16 Uranium hexafluoride [17][18][19][20][21][22][23][24][25][26] and plutonium hexafluoride [27][28][29][30][31] probably are the most studied actinide halides due to their importance in the enrichment of fission material for nuclear applications. [32][33][34] Few reports on actinide phosphates and arsenates, mainly focussing on uranium compounds [35][36][37][38][39] and/ or pre-uranium compounds [40][41][42][43][44][45][46] are available in the literature.…”
Periodic trends of trivalent actinide model systems halides AnX3, AnPO4, and AnAsO4 have been explored using scalar/spin–orbit relativistic density functional theory. The trends exhibit a pre-Pu and a post-Cm behaviour, with Am acting as the switch.
“…2,7 Halides of actinides have been synthesized in the past. 16 Uranium hexafluoride [17][18][19][20][21][22][23][24][25][26] and plutonium hexafluoride [27][28][29][30][31] probably are the most studied actinide halides due to their importance in the enrichment of fission material for nuclear applications. [32][33][34] Few reports on actinide phosphates and arsenates, mainly focussing on uranium compounds [35][36][37][38][39] and/ or pre-uranium compounds [40][41][42][43][44][45][46] are available in the literature.…”
Periodic trends of trivalent actinide model systems halides AnX3, AnPO4, and AnAsO4 have been explored using scalar/spin–orbit relativistic density functional theory. The trends exhibit a pre-Pu and a post-Cm behaviour, with Am acting as the switch.
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