Plumbic Acetate—Anhydrous Acetic Acid Solutions

Davidson, Arthur W.; Lanning, W. C.; Zeller, Sr. M. Maxine

doi:10.1021/ja01259a010

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E Halogens and Halogen Complexes In Acetic Acid1

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1953

1970

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Cited by 11 publications

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“…Detailed studies on the kinetics of the halogenation reaction by Keefer and Andrews [203][204][205] showed that in the reaction ArH + X 2 5± ArX + HX (63) the halogen acid liberated during the reaction combines with the free halogen to give the corresponding trihalide acid HX-hX 2 5±HX 3 (64) thus removing the halogen from the reaction environment. Detailed studies on the kinetics of the halogenation reaction by Keefer and Andrews [203][204][205] showed that in the reaction ArH + X 2 5± ArX + HX (63) the halogen acid liberated during the reaction combines with the free halogen to give the corresponding trihalide acid HX-hX 2 5±HX 3 (64) thus removing the halogen from the reaction environment.…”

Section: E Halogens and Halogen Complexes In Acetic Acidmentioning

confidence: 99%

Anhydrous Acetic Acid as Nonaqueous Solvent

Popov

1970

The Chemistry of Nonaqueous Solvents

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Section: E Halogens and Halogen Complexes In Acetic Acidmentioning

confidence: 99%

Anhydrous Acetic Acid as Nonaqueous Solvent

Popov

1970

The Chemistry of Nonaqueous Solvents

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Struktur der Blei(IV)‐carboxylate und ihre Zersetzung über elektronenspinresonanz‐spektroskopisch nachweisbare Radikalzwischenstufen

Heusler

Loeliger

1969

Helvetica Chimica Acta

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Summary:The position of the asymmctric COO-vibration of lead4+ carboxylatcs (at 6.50 to 6.58 p) clearly indicates the absence of covalent bonding between oxygen and lead. These salts show strong UV. absorption in the region of 220 to 270 nm which is assigned to a charge transfer from oxygen to lead. UV.-irradiation of lead4+ carboxylates at -196°C in a solid benzene matrix leads to decarboxylation and production of alkyl radicals which wcrc identified by ESR. spectrometry. These radicals react in the solid matrix by hydrogen abstraction from the a-position of a neighbouring carboxylate. In solution however rapid oxidation to carbonium ions occurs.

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Die Grundlagen der Chemie in wasserfreier Essigsäure

Maaß¹,

Jander²

1953

Fortschritte Der Chemischen Forschung

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Plumbic Acetate—Anhydrous Acetic Acid Solutions

Cited by 11 publications

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Anhydrous Acetic Acid as Nonaqueous Solvent

Anhydrous Acetic Acid as Nonaqueous Solvent

Struktur der Blei(IV)‐carboxylate und ihre Zersetzung über elektronenspinresonanz‐spektroskopisch nachweisbare Radikalzwischenstufen

Die Grundlagen der Chemie in wasserfreier Essigsäure

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