1996
DOI: 10.1557/proc-460-701
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Platinum Group Metals Base Refractory Superalloys

Abstract: Ir- and Rh-base refractory superalloys with an fee and Lb two phase structure similar to Ni-base superalloys, yet with considerably higher melting temperatures have been proposed. Fee and Ll2 two phases were observed in these alloys by transmission electron microscopy and X-ray powder diffractometry. The compression tests of these alloys showed that the strengths of several alloys were about 200 MPa at 1800 °C and these alloys have potential to become ultra-high temperature materials for use in power engineeri… Show more

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Cited by 24 publications
(14 citation statements)
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“…In both cases, the advantages of PGM-based intermetallics over Ni-based superalloys are a significantly higher melting point (ϳ1500ЊC for Pt 3 Al and ϳ2100ЊC for RuAl) and inherent oxidation resistance, albeit with some increase in density. Recent reviews of these alloys are presented by Wolff et al 18,19 and YamabeMitarai et al 20 Most of the attention has been focused on Pt-and Ru-based compounds, but there have been some studies of Ir-based 21 and Rh-based 22 materials. Progress toward the desired properties has been either by alloying to improve strength and reduce density or by oxide-dispersion strengthening (ODS).…”
Section: -17mentioning
confidence: 99%
“…In both cases, the advantages of PGM-based intermetallics over Ni-based superalloys are a significantly higher melting point (ϳ1500ЊC for Pt 3 Al and ϳ2100ЊC for RuAl) and inherent oxidation resistance, albeit with some increase in density. Recent reviews of these alloys are presented by Wolff et al 18,19 and YamabeMitarai et al 20 Most of the attention has been focused on Pt-and Ru-based compounds, but there have been some studies of Ir-based 21 and Rh-based 22 materials. Progress toward the desired properties has been either by alloying to improve strength and reduce density or by oxide-dispersion strengthening (ODS).…”
Section: -17mentioning
confidence: 99%
“…X varied between 12 at.% and 18 at.%. [6][7][8][9][10] Characterization included scanning and transmission electron microscopies and x-ray diffraction. Microscopy revealed L1 2 precipitates in a fcc matrix.…”
Section: Development Of Refractory Superalloysmentioning
confidence: 99%
“…It is necessary to search for new alloy systems with higher temperature capabilities. Among the existing intermetallic materials, the L 12 rhodium based alloys are more convenient for high temperature structural applications [2,3] due to its higher thermal conductivity, lower thermal expansion coefficient, low density and better oxidation resistance and they can also be prepared with a microstructure similar to that of nickel based alloys with enhanced ductility and workability [4e9]. Rhodium metal displays the most promising combination of properties for aerospace applications and frequently used as an alloying agent in other materials such as Platinum and Palladium.…”
Section: Introductionmentioning
confidence: 99%