Plasmonic metal‐organic frameworks

Zheng, Guangchao; Pastoriza‐Santos, Isabel; Pérez‐Juste, Jorge; Liz‐Marzán, Luis M.

doi:10.1002/smm2.1047

Cited by 68 publications

(54 citation statements)

References 151 publications

(180 reference statements)

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“…[101][102][103][104] Due to the unique and tunable optical properties of plasmonic nanomaterials, plasmon-induced chemical reactions show different mechanisms and have potential advantages over traditional photochemical reactions. [105][106][107] Surface plasmon are the collective oscillation of conduction electrons in metallic nanostructures, such as Au, Ag, and Cu nanomaterials. [108] Since the oscillation frequency of electrons matches that of light waves, the localized surface plasmon resonance will be excited.…”

Section: Plasmon-mediated Reactionsmentioning

confidence: 99%

Recent Advances in Photochemical Reactions on Single‐Molecule Electrical Platforms

Zhu

Zhao

et al. 2022

Macromol. Rapid Commun.

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The photochemical reaction is a very important type of chemical reaction. Visualizing and controlling photo-mediated reactions is a long-standing goal and challenge. In this regard, single-molecule electrical detection with label-free, real-time, and in situ characteristics has unique advantages in monitoring the dynamic process of photoreactions at the single-molecule level. In this review, a valuable summary of the latest process of single-molecule photochemical reactions based on single-molecule electrical platforms is provided. The single-molecule electrical detection platforms for monitoring photoreactions are displayed, including their fundamental principles, construction methods, and practical applications. The single-molecule studies of two different types of light-mediated reactions are summarized as below: i) photo-induced reactions, including reversible cyclization, conformational isomerization, and other photo-related reactions; ii) plasmon-mediated photoreactions, including reaction mechanisms and concrete examples, such as plasmon-induced photolysis of S-S/O-O bonds and tautomerization of porphycene. In addition, the prospects for future research directions and challenges in this field are also discussed.

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Section: Plasmon-mediated Reactionsmentioning

confidence: 99%

Recent Advances in Photochemical Reactions on Single‐Molecule Electrical Platforms

Zhu

Zhao

et al. 2022

Macromol. Rapid Commun.

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“…The photocatalytic products, such as CO and organic chemicals (HCOOH, CH 3 OH and CH 4 ), require different redox potentials -3.50 eV for CO, -3.42 eV for HCOOH, -3.65 eV for CH 3 OH and -3.79 eV for CH 4 to initiate the photocatalytic CO 2 reduction (Figs. 4(a) and 4(b)) [15,39]. As for CO production, the twoelectron photoreduction process implies a relatively low kinetic barrier.…”

Section: Photocatalysismentioning

confidence: 99%

Nanostructure@metal-organic frameworks (MOFs) for catalytic carbon dioxide (CO2) conversion in photocatalysis, electrocatalysis, and thermal catalysis

Wang

2021

Nano Res.

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The catalytic conversion of carbon dioxide (CO 2 ) into high value-added chemicals is of great significance to address the pressing carbon cycle issues. Reticular chemistry of metal-organic frameworks (MOFs)-based materials exhibits great potential and effectiveness to face CO 2 challenge from capture to conversion. To date, the integrated nanocomposites of nanostructure and MOF have emerged as a powerful heterogeneous catalysts featured with multifold advantages including synergistic effects between the two interfaces, confinement effect of meso-and micropores, tandem reaction triggered by multiple active sites, high stability and dispersion, and so on. Given burgeoning carbon cycle and nanostructure@MOFs, this review highlights some of important advancements to provide a full understanding on the synthesis and design of nanostructure@MOFs composites to facilitate carbon cycle through CO 2 photocatalytic, electrocatalytic, and thermal conversion. Afterward, the catalytic applications of some representative nanostructure@MOFs composites are categorized, in which the origin of activity or structure-activity relationship is summarized. Finally, the opportunities and challenges are proposed for inspiring the future development of nanostructure@MOFs composites for carbon cycle.

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“…Currently, numerous studies have shown that MOF-based hybrid materials could afford multifunctional properties via hybridization with other functional materials (e.g., metal nanoparticles [113][114][115][116], polymers [117,118], and other MOFs [119,120]. Similarly, combining functional components with COFs to obtain COF-based hybrid materials has also attracted widespread concerns [121][122][123][124][125][126].…”

Section: Synthesis Of Mof and Cof Hybridsmentioning

confidence: 99%

Combining metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs): Emerging opportunities for new materials and applications

Guo

Wan

et al. 2021

Nano Res.

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In the past decades, metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) basically enjoy the coordination chemistry and covalent chemistry, respectively, and such uniqueness has become the major obstacle hampering their further scope diversity and application multi-functionalization. Inspired from the principle of organic retrosynthesis, combining coordination bond and covalent bond together offers additional opportunities for constructing novel MOFs, COFs and MOF@COF hybrids as well as confer on them superior performances in versatile application fields. In this review, we firstly classify and summarize the recently reported synthesis strategies based on the integration of metal-ligand coordination and dynamic covalent bonds. Then, the application performances of as-constructed MOFs, COFs as well as MOF@COF hybrids are discussed and highlighted in the fields of adsorption, separation, catalysis, biosensing, energy storage and so on. Last, our personal insights of the remaining challenges and further prospects are also provided, in order to trigger much more inspirations and endeavors for this hot research field.

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Plasmonic metal‐organic frameworks

Cited by 68 publications

References 151 publications

Recent Advances in Photochemical Reactions on Single‐Molecule Electrical Platforms

Recent Advances in Photochemical Reactions on Single‐Molecule Electrical Platforms

Nanostructure@metal-organic frameworks (MOFs) for catalytic carbon dioxide (CO2) conversion in photocatalysis, electrocatalysis, and thermal catalysis

Combining metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs): Emerging opportunities for new materials and applications

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