Volume recombination within the Alcator C-Mod [I.H. Hutchinson et al., Phys. Plasmas 1 1511 (1994)] divertor plasma is measured and found to be a significant fraction of the total ion sink under detached divertor conditions. The recombination occurs in regions where Te ~1 eV and ne ~ 101 m-3 . Measurements of the spatial distribution of the recombination are presented. The determinations of the recombination rates are made by measuring the DO Balmer spectrum and by using a collisional radiative model describing the level populations, ionization and recombination of Do. The concept of 'recombinations per Balmer series photon' is developed to simplify the determinations. Measurements of the opacity of Lyo emission are presented. It is observed that up to 50% of the Lyo emission is trapped, indicating that Ly, is strongly trapped in some cases. The effects of Ly,, trapping on the 'recombinations per photon' curves are calculated and considered in the recombination rate determinations. Observations indicating the presence of Molecular Activated Recombination are discussed.+ Also at I.V. Kurchatov Institute of Atomic Energy, Moscow, Russian Federation