PLASMA POLYMERIZATION OF ORGANIC MONOMERS WITH ADDITION OF I<sub>2</sub>

Hirotsu, Toshihiro; Hou, Zhongke; Partridge, Ashton

doi:10.1081/ma-100101121

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Miscellaneous Polymerizations1

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2013

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“…Some plasma polymers with iodine doping are already herein mentioned. Hirotsu and Hou [122] studied the effect of the addition of small amount of molecular iodine in form of vapor on the outcome of the plasma polymerization of hydrocarbon monomers (n-hexane, cyclohexane, and benzene), N-containing monomers (pyrrole, pyridine, piperidine, pyrrolidine), and Si-containing monomers (hexamethyldisilane, hexamethyldisiloxane, and hexamethyldisilazane). The effect was mainly on the polymer deposition rate.…”

Section: Miscellaneous Polymerizationsmentioning

confidence: 99%

Molecular iodine in monomer and polymer designing

Moulay

2013

Designed Monomers and Polymers

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Not only does the molecular iodine play a leading role in organic synthesis but also in the polymer synthesis. Different kinds of polymerization initiated by molecular iodine are herein screened: cationic polymerization, radical polymerization, living/controlled radical polymerization (LCRP) such as reverse iodine transfer polymerization, polycondensation, and ring-opening polymerization (ROP). Also, the functionalization of polymers using molecular iodine, such as the acetylation of polysaccharides (cellulose, starch), and the use of iodine-polymer complex in organic synthesis are also discussed. Numerous natural and synthetic polymers are prone to make complexes with molecular iodine, and one feature of such complexes is their propensity as polymer-supported reagent and catalysts in many organic syntheses.

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Section: Miscellaneous Polymerizationsmentioning

confidence: 99%