HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. Abstract -The mechanisms responsible for etching of silicon in low pressure SF6 plasma under low energy ion impact are studied using Microwave Multipolar Plasmas. Experimental results using both mass spectrometric and etch profile analysis show the evolution of anisotropy and etch rate as a function of pressure. In particular, a transition to perfect anisotropy is observed below a threshold pressure. To account for these experimental results, a new interpretation is proposed for the surface processes observed in plasma etching. To make the current models consistent, it is necessary to add three following assumptions : i) large lateral repulsive interactions between chemisorbed fluorine atoms in nearest neighbour positions ; ii) chemisorbed fluorine atom diffusion on the silicon surface ; iii) multilayer adsorption for the Si/F system. The analytical treatment of the model points out that the etch rate is limited by the partial pressure of atomic fluorine, and that the anisotropy is controlled by the ion current density.