Hydrothermal
liquefaction (HTL) is a promising thermochemical technology
to convert wet biomass and biowastes into marketable bio-oils and
biochemicals in an environmentally friendly manner. However, industrial
deployment of this technology has been significantly hindered due
to very limited materials and corrosion knowledge for the selection
of appropriate alloys for the construction and long-term safe operation
of HTL reactors. This study investigated the influence of operating
temperature, pressure, and flow rate on the corrosion modes and extents
of two candidate constructional steels (SS310 and P91) using high-temperature
static autoclaves and environmental loop facilities under representative
HTL conversion conditions, followed by post-mortem X-ray diffraction,
X-ray photoelectron spectroscopy, scanning electron microscopy/energy-dispersive
spectroscopy, focused ion beam, and transmission electron microscopy
characterizations of the formed corrosion products. The two steels
experienced general and/or nodular oxidation in hot HTL water at 250–365
°C. Increasing temperature and flow rate resulted in a noticeable
increase in the corrosion rate of P91. For SS310, there is critical
temperature point (around 310 °C) above which its corrosion rate
decreases with temperature. Increasing flow rate suppressed the nodular
oxidation of SS310 and consequently led to a decrease in the corrosion
rate. Increasing pressure from 9.8 to 25 MPa promoted the oxide formation
on SS310 while caused an increased dissolution rate of the corrosion
layer grown on P91 steel at 310 °C. In the simulated HTL conversion
environments, the corrosion layer on P91 was mainly composed of magnetite
(Fe3O4) and chromite (Fe3–x
Cr
x
O4), while
a compact and protective inner Cr-enriched layer was formed on SS310
along with the presence of other cations. Related corrosion mechanisms
were also discussed and proposed.