In C02-N2-He electric-discharge lasers, small concentrations of impurities may be present in the original gases, or new species may be generated by the discharge. In order to determine the effects of such impurities, controlled amounts of possible contaminants were introduced into the amplifier of a C 0 2 probe-amplifier system. Smallsignal gain was reduced in all cases when CO, 02, NO, NzO, or NO2 molecules were added. It was found that less than 0.1 percent of NO2 or N 2 0 markedly reduces the laser gain and alters the discharge impedance. A discharge model which describes a three-component positivecolumn plasma (electrons, positive ions, and negative ions) yields results consistent with the observations. The influence of attachment and detachment rates on molecular gas discharge characteristics and stability are studied.
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INTRODUCTIONHE C 0 2 dc discharge laser operates at high efficiency in the glow discharge mode with an optimum mixture of C 0 2 , N 2 , and He which depends on the total pressure, flow rate, current density, and discharge geometry [ I ] . The operating conditions for a given geometry of this weakly ionized plasma (n'/N= are determined by a self-consistent balance of charged-particle production and loss. The discharge properties are controlled by collisional kinetics, plasma chemistry, laser operation, and boundary conditions.In those papers dealing with mass-spectrometric measurements of C 0 2 laser discharges [2] -[ 6 ] the main emphasis has been on the rate of dissociation of C 0 2 into CO and O2 and how this dissociation is changed by operating conditions or gas additives. However, the possible effects on laser performance of the other minor species that are known to exist [7] have not been measured. Therefore, the purpose of the present study was to determine the influence of nitrogen oxides and other candidate dissociation products on the discharge properties and optical gain characteristics of a C 0 2 laser.
EXPERIMENTCalibrated amounts of contaminant gases were added to an open-cycle flowing C 0 2 -N2 -He laser discharge. Discharge voltage and small-signal gain were monitored as functions of current. The discharges studied were at total pressures of 5 , Patterson Air Force Base, Ohio 45433. P. D. Tannen was with the Aerospace Research Laboratories, WrightPatterson Air Force Base, Ohio 45433. He is now with the Air Force Weapons Laboratory, Kirtland Air Force Base, N. Mex.10, and 15 torr. The amplifier-tube active length was approximately 57 cm between hollow Kovar electrodes in a watercooled Pyrex tube, with a 22-mm internal diameter (ID). The gas flow rates of C02-N2-He were in the ratio 5 : 10: 85, and the gas residence time in the discharge was approximately 20 ms.A frequency stable laser,' operating on the P20 line of the 10.6-1.1 transitions, was used to measure small-signal gain. The intensities of the reference and amplified beam were measured simultaneously using thermocouples with digital readouts. To compensate for any fluctuations in the probe oscillator output power, the...